CAS OpenIR  > 中科院上海原子核所2003年前
Molecular inductive effect index and boiling point of aliphatic aldehydes and alkanones
Zhang, XL(张秀利); Wang, YX(汪勇先); Li, JL; Lin, YW
2002
Source PublicationCHINESE JOURNAL OF ORGANIC CHEMISTRY
ISSN0253-2786
Volume22Issue:11Pages:897
AbstractBased on the molecular inductive effect index, a formula consisting of three parameters was proposed to calculate the boiling point of aliphatic aldehydes and alkanones. In( 820.5 - T-b) = 6.38327 - 23961 x 10(-1) N-e + 1.95353DeltaI + 6.68434 x 10(-2) N, where the N-e is the effective length of carbon chain of alkyl group in the aliphatic aldehydes and allcanones. The DeltaI is the inductive effect index difference between the corresponding branched and normal alkyl isomer containing the same carbon atom number, which expresses the effect of carbonyl group on the boiling point of aliphatic aldehydes and alkanones. N is the numbers of carbon atoms of aliphatic aldehydes and alkanones.
Indexed BySCI
Language英语
Funding Project应物所项目组
WOS IDWOS:000179212500015
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/10065
Collection中科院上海原子核所2003年前
Recommended Citation
GB/T 7714
Zhang, XL,Wang, YX,Li, JL,et al. Molecular inductive effect index and boiling point of aliphatic aldehydes and alkanones[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2002,22(11):897.
APA Zhang, XL,Wang, YX,Li, JL,&Lin, YW.(2002).Molecular inductive effect index and boiling point of aliphatic aldehydes and alkanones.CHINESE JOURNAL OF ORGANIC CHEMISTRY,22(11),897.
MLA Zhang, XL,et al."Molecular inductive effect index and boiling point of aliphatic aldehydes and alkanones".CHINESE JOURNAL OF ORGANIC CHEMISTRY 22.11(2002):897.
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