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Oxidative splitting of a pyrimidine cyclobutane dimer: A pulse radiolysis study | |
Yan, LQ; Song, QH; Hei, XM; Guo, QX; Lin, WZ(林维真) | |
2003 | |
Source Publication | CHINESE JOURNAL OF CHEMISTRY
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ISSN | 1001-604X |
Volume | 21Issue:1Pages:16 |
Abstract | The oxidative splitting process of cis-syn 1,3-dimethyluracil cyclobutane dimer (DMUD) in aqueous solution was investigated using pulse radiolysis technique. The results indicated that DMUD can be splitted into 1,3-dimethyluracil (DMU) by OH radicals (OH.) and Br-2 radical anions (Br-2(.-)), but not by azide radicals (N-3(.)). The oxidative mechanisms that an H abstracted from DMUD for Off oxidative splitting and an electron transfer from DMUD to Br-2(.-), were suggested. Related kinetic parameters were determined. |
Indexed By | SCI |
Language | 英语 |
Funding Project | 应物所项目组 |
WOS ID | WOS:000180197000005 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/10092 |
Collection | 中科院上海原子核所2003年前 |
Recommended Citation GB/T 7714 | Yan, LQ,Song, QH,Hei, XM,et al. Oxidative splitting of a pyrimidine cyclobutane dimer: A pulse radiolysis study[J]. CHINESE JOURNAL OF CHEMISTRY,2003,21(1):16. |
APA | Yan, LQ,Song, QH,Hei, XM,Guo, QX,&Lin, WZ.(2003).Oxidative splitting of a pyrimidine cyclobutane dimer: A pulse radiolysis study.CHINESE JOURNAL OF CHEMISTRY,21(1),16. |
MLA | Yan, LQ,et al."Oxidative splitting of a pyrimidine cyclobutane dimer: A pulse radiolysis study".CHINESE JOURNAL OF CHEMISTRY 21.1(2003):16. |
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