Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
Reaction of carotenoids with CCl3OO by using pulse radiolysis | |
Zhao, WN; Yao, S(姚思德); Wang, Q; Qian, SP; Wang, WF(王文峰); Han, YS | |
2003 | |
Source Publication | SCIENCE IN CHINA SERIES B-CHEMISTRY
![]() |
ISSN | 1006-9291 |
Volume | 46Issue:1Pages:57 |
Abstract | The interactions of carotenoids (bixin, P-carotene and lycopene) with CCl3OO. in aqueous and i-propylalcohol solution saturated with air have been studied by pulse radiolysis. For bixin and beta-carotene reaction products from forming process, absorbing in the region of 650 nm, is observed with concomitant carotenoid bleaching (bixin at 500 nm, beta-carotene at 450 nm). Their rate constants from forming process are 1.78 X 10(8) and 7.8 X 10(7) mol(-1) . L . s(-1) respectively. However, in the case of lycopene, no such a forming process of reaction as bixin and beta-carotene can be observed although there is the bleaching reaction (rate constant 4 X 107 mol(-1) . L . s(-1)). The results suggest that the carotenoid radical cation and an additional radical are produced in the case of bixin and-p-carotene, whereas lycopene undergoes electron transfer with CCl3OO., forming cation radical. |
Indexed By | SCI |
Language | 英语 |
Funding Project | 应物所项目组 |
WOS ID | WOS:000181415100009 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/10142 |
Collection | 中科院上海原子核所2003年前 |
Recommended Citation GB/T 7714 | Zhao, WN,Yao, S,Wang, Q,et al. Reaction of carotenoids with CCl3OO by using pulse radiolysis[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2003,46(1):57. |
APA | Zhao, WN,Yao, S,Wang, Q,Qian, SP,Wang, WF,&Han, YS.(2003).Reaction of carotenoids with CCl3OO by using pulse radiolysis.SCIENCE IN CHINA SERIES B-CHEMISTRY,46(1),57. |
MLA | Zhao, WN,et al."Reaction of carotenoids with CCl3OO by using pulse radiolysis".SCIENCE IN CHINA SERIES B-CHEMISTRY 46.1(2003):57. |
Files in This Item: | Download All | |||||
File Name/Size | DocType | Version | Access | License | ||
Reaction of caroteno(155KB) | 开放获取 | -- | View Download |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment