CAS OpenIR  > 中科院上海原子核所2003年前
The importance of mesomerism in the termination of alpha-carboxymethyl radicals from aqueous malonic and acetic acids
Wang, WF(王文锋); Schuchmann, MN; Schuchmann, HP; von Sonntag, C
2001
Source PublicationCHEMISTRY-A EUROPEAN JOURNAL
ISSN0947-6539
Volume7Issue:4Pages:791
AbstractIn the dioxygen-free aqueous malonic and acetic acid systems, alpha -carboxymethyl radicals are produced through hydrogen abstraction from the parent compound by radiolytically generated OH radicals. H abstraction from the CO2-/ CO2H group followed by decarboxylation is a process of small importance (less than or equal to5%). The alpha -carboxymethyl radicals terminate by recombination. Two types of recombination product are observed which are characterised by the formation of a C-C linkage or a C-O linkage. alpha -Carboxymethyl radicals are mesomeric systems, Their mesomeric state depends on the state of protonation and determines the proportion of the C-C- versus C-O-linked dehydrodimers they produce.
Indexed BySCI
Language英语
Funding Project应物所项目组
WOS IDWOS:000167138500005
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/10218
Collection中科院上海原子核所2003年前
Recommended Citation
GB/T 7714
Wang, WF,Schuchmann, MN,Schuchmann, HP,et al. The importance of mesomerism in the termination of alpha-carboxymethyl radicals from aqueous malonic and acetic acids[J]. CHEMISTRY-A EUROPEAN JOURNAL,2001,7(4):791.
APA Wang, WF,Schuchmann, MN,Schuchmann, HP,&von Sonntag, C.(2001).The importance of mesomerism in the termination of alpha-carboxymethyl radicals from aqueous malonic and acetic acids.CHEMISTRY-A EUROPEAN JOURNAL,7(4),791.
MLA Wang, WF,et al."The importance of mesomerism in the termination of alpha-carboxymethyl radicals from aqueous malonic and acetic acids".CHEMISTRY-A EUROPEAN JOURNAL 7.4(2001):791.
Files in This Item: Download All
File Name/Size DocType Version Access License
The importance of me(101KB) 开放获取--View Download
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Wang, WF(王文锋)]'s Articles
[Schuchmann, MN]'s Articles
[Schuchmann, HP]'s Articles
Baidu academic
Similar articles in Baidu academic
[Wang, WF(王文锋)]'s Articles
[Schuchmann, MN]'s Articles
[Schuchmann, HP]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Wang, WF(王文锋)]'s Articles
[Schuchmann, MN]'s Articles
[Schuchmann, HP]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: The importance of mesomerism in the termination of alpha-carboxymethyl radicals from aqueous malonic and acetic acids.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.