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The Reaction Mechanism Study of C_(60) and CH_3CCl_3 by Pulse Radiolysis and Laser Photolysis
Wang CC(汪朝存); Yao SD(姚思德)
1998-04-10
Source Publication化学物理学报
Issue02
Other Abstract用脉冲辐解激光光解技术研究C60和CH3CCl3的反应机理;发现C60在650nm有特征吸收;认为在脉冲辐解实验中是通过空穴转移(由CH3CCl+·3向C60进行空穴转移而产生C+·60)以及在激光光解实验中通过激光态转移(由3C*60向CH3CCl3转移而产生C+·60)两种不同的机制产生的。另外;在430nm处观察到C60和CH3CCl3的长寿命自由基加合物的产生;认为这个自由基加合物在脉冲辐解和激光光解过程中分别以自由基加成机制和通过形成激发态络合物两种不同的机制产生的。
Indexed ByCNKI
Language中文
Funding Project原子核所项目组
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/11035
Collection中科院上海原子核所2003年前
Recommended Citation
GB/T 7714
Wang CC,Yao SD. The Reaction Mechanism Study of C_(60) and CH_3CCl_3 by Pulse Radiolysis and Laser Photolysis[J]. 化学物理学报,1998(02).
APA 汪朝存,&姚思德.(1998).The Reaction Mechanism Study of C_(60) and CH_3CCl_3 by Pulse Radiolysis and Laser Photolysis.化学物理学报(02).
MLA 汪朝存,et al."The Reaction Mechanism Study of C_(60) and CH_3CCl_3 by Pulse Radiolysis and Laser Photolysis".化学物理学报 .02(1998).
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