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二硝酸二(N-月桂酰吡咯烷)合铀酰配合物的合成和结构
韩景田; 包伯荣; 孙国新; 杨勇; 杨永会; 陈民勤; 孙思修
2000-10-20
Source Publication化学学报
Issue10
Abstract报道了N-月桂酰吡咯烷(DOPOD)与硝酸铀酰形成的配合物晶体的合成、表征和结构.由元素分析及红外光谱确定了萃合物的组成UO_2(DOPOD)_2(NO_3)_2;该晶体属正交晶系;空间群为Pbca.配合物中铀酰离子由六个氧原子配位;其中四个来自硝酸根;另两个来自两个DOPOD配体.两硝酸根和两个DOPOD配体分别处于对位位置;形成以铀原子为中心的六方双锥结构.在构象上;两个DOPOD配体的长碳链及五元杂环处于顺式构象位置.
Indexed ByCNKI
Language中文
Funding Project原子核所项目组
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/11326
Collection中科院上海原子核所2003年前
Recommended Citation
GB/T 7714
韩景田,包伯荣,孙国新,等. 二硝酸二(N-月桂酰吡咯烷)合铀酰配合物的合成和结构[J]. 化学学报,2000(10).
APA 韩景田.,包伯荣.,孙国新.,杨勇.,杨永会.,...&孙思修.(2000).二硝酸二(N-月桂酰吡咯烷)合铀酰配合物的合成和结构.化学学报(10).
MLA 韩景田,et al."二硝酸二(N-月桂酰吡咯烷)合铀酰配合物的合成和结构".化学学报 .10(2000).
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