Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
Propylene Epoxidation by Dioxygen over Catalyst Copper-loaded TiO2 | |
Jin Qiang-wei; Wang Kai-xue; Wang Jian-qiang(王建强); Li Xiao-bei; Chen Jie-sheng | |
2011 | |
Source Publication | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
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ISSN | 1005-9040 |
Volume | 27Issue:5Pages:866 |
Abstract | A copper-TiO2 based catalyst(Cu-OH-Cl-TiO2) was prepared through a slurry impregnation approach and the catalyst was found to be active and selective for the epoxidation of propylene by dioxygen. With a feed gas of 10% C3H6, 10% O-2 and 80% N-2 at a gas hourly space velocity(GHSV) of 4000 h(-1), a propylene conversion of 4.8% and a propylene oxide(PO) selectivity of 38.9% were achieved over the obtained Cu-OH-Cl-TiO2 catalyst at a reaction temperature of 500 K. It revealed that Cu2+ provided by crystalline Cu-2(OH)(3)Cl plays a key role in catalytic conversion of propylene to PO. |
Indexed By | SCI |
Language | 英语 |
Funding Project | 应物所项目组 |
WOS ID | WOS:000296120800034 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/12874 |
Collection | 中科院上海应用物理研究所2011-2020年 |
Recommended Citation GB/T 7714 | Jin Qiang-wei,Wang Kai-xue,Wang Jian-qiang,et al. Propylene Epoxidation by Dioxygen over Catalyst Copper-loaded TiO2[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2011,27(5):866. |
APA | Jin Qiang-wei,Wang Kai-xue,Wang Jian-qiang,Li Xiao-bei,&Chen Jie-sheng.(2011).Propylene Epoxidation by Dioxygen over Catalyst Copper-loaded TiO2.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,27(5),866. |
MLA | Jin Qiang-wei,et al."Propylene Epoxidation by Dioxygen over Catalyst Copper-loaded TiO2".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 27.5(2011):866. |
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