Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Using stannous ion as an excellent inorganic ECL coreactant for tris(2,2 '-bipyridyl) ruthenium(II) | |
| Zheng, LY; Wang, BB; Chi, YW; Song, SH（宋世平）; Fan, CH（樊春海）; Chen, GN | |
| 2012 | |
| Source Publication | DALTON TRANSACTIONS
 |
| ISSN | 1477-9226 |
| Volume | 41Issue:5 |
| Abstract | It was found that stannous chloride (SnCl(2)), as a popular inorganic reducing reagent, could obviously enhance the electrochemiluminescence (ECL) of tris(2,2'-bipyridyl) ruthenium(II) (Ru(bpy)(3)(2+)) in aqueous solution. Some factors affecting the ECL reactions between Ru(bpy)(3)(2+) and Sn(2+), including pH, concentrations of coreactant, and electrode materials, were investigated by comparison with a classic ECL coreactant tripropylamine (TPA). The Ru(bpy)(3)(2+)-Sn(2+) ECL coreactant system produces stronger and more stable ECL signals, can keep its excellent ECL activity over a wider pH range and has more choices in using electrode materials than the Ru(bpy)(3)(2+)-TPA ECL coreactant system. The ECL mechanism of the Ru(bpy)(3)(2+)-Sn(2+) coreactant system was also studied in detail. |
| Language | 英语 |
| Funding Project | 应物所项目组 |
| WOS ID | WOS:000299054500030 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/13338 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Recommended Citation GB/T 7714 | Zheng, LY,Wang, BB,Chi, YW,et al. Using stannous ion as an excellent inorganic ECL coreactant for tris(2,2 '-bipyridyl) ruthenium(II)[J]. DALTON TRANSACTIONS,2012,41(5). |
| APA | Zheng, LY,Wang, BB,Chi, YW,Song, SH,Fan, CH,&Chen, GN.(2012).Using stannous ion as an excellent inorganic ECL coreactant for tris(2,2 '-bipyridyl) ruthenium(II).DALTON TRANSACTIONS,41(5). |
| MLA | Zheng, LY,et al."Using stannous ion as an excellent inorganic ECL coreactant for tris(2,2 '-bipyridyl) ruthenium(II)".DALTON TRANSACTIONS 41.5(2012). |
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| File Name/Size | DocType | Version | Access | License | ||
| Using stannous ion a（1176KB） | 开放获取 | CC BY-NC-SA | View Application Full Text | |||
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