CAS OpenIR  > 中科院上海应用物理研究所2011-2019年
Using stannous ion as an excellent inorganic ECL coreactant for tris(2,2 '-bipyridyl) ruthenium(II)
Zheng, LY; Wang, BB; Chi, YW; Song, SH(宋世平); Fan, CH(樊春海); Chen, GN
2012
Source PublicationDALTON TRANSACTIONS
ISSN1477-9226
Volume41Issue:5
AbstractIt was found that stannous chloride (SnCl(2)), as a popular inorganic reducing reagent, could obviously enhance the electrochemiluminescence (ECL) of tris(2,2'-bipyridyl) ruthenium(II) (Ru(bpy)(3)(2+)) in aqueous solution. Some factors affecting the ECL reactions between Ru(bpy)(3)(2+) and Sn(2+), including pH, concentrations of coreactant, and electrode materials, were investigated by comparison with a classic ECL coreactant tripropylamine (TPA). The Ru(bpy)(3)(2+)-Sn(2+) ECL coreactant system produces stronger and more stable ECL signals, can keep its excellent ECL activity over a wider pH range and has more choices in using electrode materials than the Ru(bpy)(3)(2+)-TPA ECL coreactant system. The ECL mechanism of the Ru(bpy)(3)(2+)-Sn(2+) coreactant system was also studied in detail.
Language英语
Funding Project应物所项目组
WOS IDWOS:000299054500030
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/13338
Collection中科院上海应用物理研究所2011-2019年
Recommended Citation
GB/T 7714
Zheng, LY,Wang, BB,Chi, YW,et al. Using stannous ion as an excellent inorganic ECL coreactant for tris(2,2 '-bipyridyl) ruthenium(II)[J]. DALTON TRANSACTIONS,2012,41(5).
APA Zheng, LY,Wang, BB,Chi, YW,Song, SH,Fan, CH,&Chen, GN.(2012).Using stannous ion as an excellent inorganic ECL coreactant for tris(2,2 '-bipyridyl) ruthenium(II).DALTON TRANSACTIONS,41(5).
MLA Zheng, LY,et al."Using stannous ion as an excellent inorganic ECL coreactant for tris(2,2 '-bipyridyl) ruthenium(II)".DALTON TRANSACTIONS 41.5(2012).
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