CAS OpenIR  > 中科院上海应用物理研究所2011-2019年
Catalytic conversion of biomass-derived levulinic acid into gamma-valerolactone using iridium nanoparticles supported on carbon nanotubes
Du Xianlong; Liu Yongmei; Wang Jianqiang(王建强); Cao Yong; Fan Kangnian
2013
Source PublicationCHINESE JOURNAL OF CATALYSIS
ISSN0253-9837
Volume34Issue:5Pages:CONCATENATE(Sheet1!I49,-Sheet1!J49)
AbstractA new method has been developed for the catalytic conversion of biomass-derived levulinic acid (LA) into gamma-valerolactone (GVL) with molecular hydrogen (H-2) using a series of heterogeneous noble metal catalysts. Excellent yields of the GVL were obtained under mild reaction conditions of 50 degrees C and 2 MPa of H-2 using iridium nanoparticles supported on carbon nanotubes (Ir/CNT). It is noteworthy that the reaction proceeded smoothly in the presence of formic acid (FA, co-produced with LA in equimolar amounts during the acid-mediated hydrolysis of lignocellulosic biomass). Furthermore, the FA remained intact, highlighting the practical advantages of this process for the convenient and cost-effective processing of a biomass-derived LA/FA solution. The method is effective for the simultaneous production of GVL and FA from a wide variety of renewable biomass resources. (C) 2013, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
Indexed BySCI
Language英语
Funding Project应物所项目组
WOS IDWOS:000318744600022
Citation statistics
Cited Times:50[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/13685
Collection中科院上海应用物理研究所2011-2019年
Recommended Citation
GB/T 7714
Du Xianlong,Liu Yongmei,Wang Jianqiang,et al. Catalytic conversion of biomass-derived levulinic acid into gamma-valerolactone using iridium nanoparticles supported on carbon nanotubes[J]. CHINESE JOURNAL OF CATALYSIS,2013,34(5):CONCATENATE(Sheet1!I49,-Sheet1!J49).
APA Du Xianlong,Liu Yongmei,Wang Jianqiang,Cao Yong,&Fan Kangnian.(2013).Catalytic conversion of biomass-derived levulinic acid into gamma-valerolactone using iridium nanoparticles supported on carbon nanotubes.CHINESE JOURNAL OF CATALYSIS,34(5),CONCATENATE(Sheet1!I49,-Sheet1!J49).
MLA Du Xianlong,et al."Catalytic conversion of biomass-derived levulinic acid into gamma-valerolactone using iridium nanoparticles supported on carbon nanotubes".CHINESE JOURNAL OF CATALYSIS 34.5(2013):CONCATENATE(Sheet1!I49,-Sheet1!J49).
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