Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Catalytic conversion of biomass-derived levulinic acid into gamma-valerolactone using iridium nanoparticles supported on carbon nanotubes | |
| Du Xianlong; Liu Yongmei; Wang Jianqiang（王建强）; Cao Yong; Fan Kangnian | |
| 2013 | |
| Source Publication | CHINESE JOURNAL OF CATALYSIS
 |
| ISSN | 0253-9837 |
| Volume | 34Issue:5Pages:CONCATENATE(Sheet1!I49,-Sheet1!J49) |
| Abstract | A new method has been developed for the catalytic conversion of biomass-derived levulinic acid (LA) into gamma-valerolactone (GVL) with molecular hydrogen (H-2) using a series of heterogeneous noble metal catalysts. Excellent yields of the GVL were obtained under mild reaction conditions of 50 degrees C and 2 MPa of H-2 using iridium nanoparticles supported on carbon nanotubes (Ir/CNT). It is noteworthy that the reaction proceeded smoothly in the presence of formic acid (FA, co-produced with LA in equimolar amounts during the acid-mediated hydrolysis of lignocellulosic biomass). Furthermore, the FA remained intact, highlighting the practical advantages of this process for the convenient and cost-effective processing of a biomass-derived LA/FA solution. The method is effective for the simultaneous production of GVL and FA from a wide variety of renewable biomass resources. (C) 2013, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 应物所项目组 |
| WOS ID | WOS:000318744600022 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/13685 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Recommended Citation GB/T 7714 | Du Xianlong,Liu Yongmei,Wang Jianqiang,et al. Catalytic conversion of biomass-derived levulinic acid into gamma-valerolactone using iridium nanoparticles supported on carbon nanotubes[J]. CHINESE JOURNAL OF CATALYSIS,2013,34(5):CONCATENATE(Sheet1!I49,-Sheet1!J49). |
| APA | Du Xianlong,Liu Yongmei,Wang Jianqiang,Cao Yong,&Fan Kangnian.(2013).Catalytic conversion of biomass-derived levulinic acid into gamma-valerolactone using iridium nanoparticles supported on carbon nanotubes.CHINESE JOURNAL OF CATALYSIS,34(5),CONCATENATE(Sheet1!I49,-Sheet1!J49). |
| MLA | Du Xianlong,et al."Catalytic conversion of biomass-derived levulinic acid into gamma-valerolactone using iridium nanoparticles supported on carbon nanotubes".CHINESE JOURNAL OF CATALYSIS 34.5(2013):CONCATENATE(Sheet1!I49,-Sheet1!J49). |
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| Catalytic conversion（2021KB） | 开放获取 | CC BY-NC-SA | View Download | |||
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