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Large Strain Response in 0.99(Bi0.5Na0.4K0.1)TiO3-0.01(KxNa1-x)NbO3 Lead-Free Ceramics Induced by the Change of K/Na Ratio in (KxNa1-x)NbO3 | |
Hao, Jigong; Shen, Bo; Zhai, Jiwei; Liu, Chunze; Li, Xiaolong; Gao, Xingyu | |
2013 | |
Source Publication | JOURNAL OF THE AMERICAN CERAMIC SOCIETY
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ISSN | 0002-7820; 1551-2916 |
Volume | 96Issue:10Pages:CONCATENATE(Sheet1!I189,-Sheet1!J189) |
Abstract | Influence of K/Na ratio in (KxNa1-x)NbO3 on the ferroelectric stability and consequent changes in the electrical properties of 0.99(Bi0.5Na0.4K0.1)TiO3-0.01(KxNa1-x)NbO3 (BNKT-KxNN) ceramics were investigated. Results showed that change of K/Na ratio in KNN induces a phase transition from ferroelectric to ergodic relaxor phase with a significant disruption of the long-range ferroelectric order, and correspondingly adjusts the ferroelectric-relaxor transition point TF-R to room temperature. Accordingly, giant strain of 0.46% (corresponding to a large signal d(33)* of 575pm/V) which is comparable to that of Pb-based antiferroelectrics is obtained at a K/Na ratio of 1, and the emergence of large strain response induced by the change of K/Na ratio of KNN can be well explained by the correlation between the position of ferroelectric-ergodic relaxor phase boundary in the BNKT-KxNN system and the tolerance factor t of the end number (KxNN). In situ high-energy X-ray scattering experiments with external field reveals that the large strain response in the studied system is likely related to the electric field-induced distortion from the pseudocubic structure. |
Indexed By | SCI |
Language | 英语 |
Funding Project | 应物所项目组 |
WOS ID | WOS:000329152200022 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/13801 |
Collection | 中科院上海应用物理研究所2011-2020年 |
Recommended Citation GB/T 7714 | Hao, Jigong,Shen, Bo,Zhai, Jiwei,et al. Large Strain Response in 0.99(Bi0.5Na0.4K0.1)TiO3-0.01(KxNa1-x)NbO3 Lead-Free Ceramics Induced by the Change of K/Na Ratio in (KxNa1-x)NbO3[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY,2013,96(10):CONCATENATE(Sheet1!I189,-Sheet1!J189). |
APA | Hao, Jigong,Shen, Bo,Zhai, Jiwei,Liu, Chunze,Li, Xiaolong,&Gao, Xingyu.(2013).Large Strain Response in 0.99(Bi0.5Na0.4K0.1)TiO3-0.01(KxNa1-x)NbO3 Lead-Free Ceramics Induced by the Change of K/Na Ratio in (KxNa1-x)NbO3.JOURNAL OF THE AMERICAN CERAMIC SOCIETY,96(10),CONCATENATE(Sheet1!I189,-Sheet1!J189). |
MLA | Hao, Jigong,et al."Large Strain Response in 0.99(Bi0.5Na0.4K0.1)TiO3-0.01(KxNa1-x)NbO3 Lead-Free Ceramics Induced by the Change of K/Na Ratio in (KxNa1-x)NbO3".JOURNAL OF THE AMERICAN CERAMIC SOCIETY 96.10(2013):CONCATENATE(Sheet1!I189,-Sheet1!J189). |
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