CAS OpenIR  > 中科院上海应用物理研究所2011-2019年
Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder
Huang, Ya-Xi; Liu, Biao; Wen, Lei; Zhang, Xin; Sun, Wei; Lin, Jun; Huang, Chun-Zuo; Zhuang, Rong-Chuan; Mi, Jin-Xiao; Zhao, Jing-Tai
2013
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume52Issue:16Pages:CONCATENATE(Sheet1!I318,-Sheet1!J318)
AbstractStructural assembly from phosphate to germanophosphate by applying germanate as a binder has been achieved. Two isotypic porous compounds, K-3 [M-4(II)(HPO4)(2)][Ge2O(OH)(PO4)(4)]center dot xH(2)O (M-II = Fe, Cd; x = 2 for Fe and 3 for Cd, denoted as KFeGePO-1 and KCdGePO-1, respectively), contain a known transition-metal phosphate (TMPO) layer, (2)(infinity){[M-2(HPO4)(3)](2-)}, which is built from chains of trans-edge-sharing MO6 octahedra bridged by MO5 trigonal bipyramids that were further linked and decorated by phosphate tetrahedra. The layers are bound by infinite chains of GeO5(OH) octahedra, resulting in a 3D open-framework structure with 1D 12-ring channels that are occupied by K+ ions and water molecules. The curvature of the TMPO layers and shape of the 12-ring windows can be tuned by the transition metals because of their Jahn-Teller effect.
Indexed BySCI
Language英语
Funding Project应物所项目组
WOS IDWOS:000323460800003
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/13917
Collection中科院上海应用物理研究所2011-2019年
Recommended Citation
GB/T 7714
Huang, Ya-Xi,Liu, Biao,Wen, Lei,et al. Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder[J]. INORGANIC CHEMISTRY,2013,52(16):CONCATENATE(Sheet1!I318,-Sheet1!J318).
APA Huang, Ya-Xi.,Liu, Biao.,Wen, Lei.,Zhang, Xin.,Sun, Wei.,...&Zhao, Jing-Tai.(2013).Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder.INORGANIC CHEMISTRY,52(16),CONCATENATE(Sheet1!I318,-Sheet1!J318).
MLA Huang, Ya-Xi,et al."Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder".INORGANIC CHEMISTRY 52.16(2013):CONCATENATE(Sheet1!I318,-Sheet1!J318).
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