CAS OpenIR  > 中科院上海应用物理研究所2011-2019年
An Aqueous Rechargeable Formate-Based Hydrogen Battery Driven by Heterogeneous Pd Catalysis
Bi, QY; Lin, JD; Liu, YM; Du, XL; Wang, JQ; He, HY; Cao, Y; yongcao@fudan.edu.cn
2014
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN1433-7851
Volume53Issue:49Pages:13583—13587
AbstractThe formate-based rechargeable hydrogen battery (RHB) promises high reversible capacity to meet the need for safe, reliable, and sustainable H-2 storage used in fuel cell applications. Described herein is an additive-free RHB which is based on repetitive cycles operated between aqueous formate dehydrogenation (discharging) and bicarbonate hydrogenation (charging). Key to this truly efficient and durable H-2 handling system is the use of highly strained Pd nanoparticles anchored on graphite oxide nanosheets as a robust and efficient solid catalyst, which can facilitate both the discharging and charging processes in a reversible and highly facile manner. Up to six repeated discharging/charging cycles can be performed without noticeable degradation in the storage capacity.
KeywordFormic-acid Decomposition Carbon-dioxide Reversible Hydrogenation Ambient Conditions Storage Material Lattice Strain Co2 Derivatives Generation Particles
Indexed BySCI
Language英语
WOS IDWOS:000345590300051
Citation statistics
Cited Times:81[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/14006
Collection中科院上海应用物理研究所2011-2019年
Corresponding Authoryongcao@fudan.edu.cn
Recommended Citation
GB/T 7714
Bi, QY,Lin, JD,Liu, YM,et al. An Aqueous Rechargeable Formate-Based Hydrogen Battery Driven by Heterogeneous Pd Catalysis[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(49):13583—13587.
APA Bi, QY.,Lin, JD.,Liu, YM.,Du, XL.,Wang, JQ.,...&yongcao@fudan.edu.cn.(2014).An Aqueous Rechargeable Formate-Based Hydrogen Battery Driven by Heterogeneous Pd Catalysis.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(49),13583—13587.
MLA Bi, QY,et al."An Aqueous Rechargeable Formate-Based Hydrogen Battery Driven by Heterogeneous Pd Catalysis".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.49(2014):13583—13587.
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