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Deformation temperature and lamellar thickness dependency of Form I to Form III phase transition in syndiotactic polypropylene during tensile stretching | |
Lu, Y; Sun, YY; Chen, R; Li, XH; Men, YF; men@ciac.ac.cn | |
2014 | |
Source Publication | CHINESE JOURNAL OF POLYMER SCIENCE
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ISSN | 0256-7679 |
Volume | 32Issue:9Pages:1210—1217 |
Abstract | Phase transition from form I to form III in syndiotactic polypropylene crystallized at different conditions during tensile deformation at different temperatures was investigated by using in situ synchrotron wide angle X-ray diffraction technique. In all cases, the occurrence of this phase transition was observed. The onset strain of this transition was found to be crystalline thickness decided by crystallization temperature and drawing temperature dependent. The effect of drawing temperature on this phase transition is understood by the changes in mechanical properties with temperature. Moreover, crystalline thickness dependency of the phase transition reveals that this form I to from III phase transition occurs first in those lamellae with their normal along the stretching direction which have not experienced stress induced melting and recrystallization. |
Keyword | Planar Zigzag Form Low-density Polyethylene X-ray-scattering 0 Degrees-c Crystal-structure Spontaneous Crystallization Mesomorphic Form Behavior Morphology Polymers |
Indexed By | SCI |
Language | 英语 |
WOS ID | WOS:000339881900010 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/14065 |
Collection | 中科院上海应用物理研究所2011-2020年 |
Corresponding Author | men@ciac.ac.cn |
Recommended Citation GB/T 7714 | Lu, Y,Sun, YY,Chen, R,et al. Deformation temperature and lamellar thickness dependency of Form I to Form III phase transition in syndiotactic polypropylene during tensile stretching[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2014,32(9):1210—1217. |
APA | Lu, Y,Sun, YY,Chen, R,Li, XH,Men, YF,&men@ciac.ac.cn.(2014).Deformation temperature and lamellar thickness dependency of Form I to Form III phase transition in syndiotactic polypropylene during tensile stretching.CHINESE JOURNAL OF POLYMER SCIENCE,32(9),1210—1217. |
MLA | Lu, Y,et al."Deformation temperature and lamellar thickness dependency of Form I to Form III phase transition in syndiotactic polypropylene during tensile stretching".CHINESE JOURNAL OF POLYMER SCIENCE 32.9(2014):1210—1217. |
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