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Enhancing Proton Conduction in 2D Co-La Coordination Frameworks by Solid-State Phase Transition
Bao, SS; Otsubo, K; Taylor, JM; Jiang, Z; Zheng, LM; Kitagawa, H; lmzheng@nju.edu.cn; kitagawa@kuchem.kyoto-u.ac.jp
2014
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
Volume136Issue:26Pages:9292—9295
AbstractWe report that a new 2D 3d-4f phosphonate [(CoLaIII)-La-III(notpH)(H2O)(6)]ClO4 center dot 5H(2)O (CoLa-II) can undergo a phase transition above 45 degrees C and 93% relative humidity, resulting in [H3O][CoLa(notp)-(H2O)(4)]ClO4 center dot 3H(2)O (CoLa-III). The transition is accompanied by the release of the proton from intralayer to interlayer, and thus the proton conductivity of the material is increased by 1 order of magnitude.
KeywordMetal-organic Framework Polymers Clusters Crystal Mof
Indexed BySCI
Language英语
WOS IDWOS:000338692700015
Citation statistics
Cited Times:108[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/14120
Collection中科院上海应用物理研究所2011-2020年
Corresponding Authorlmzheng@nju.edu.cn; kitagawa@kuchem.kyoto-u.ac.jp
Recommended Citation
GB/T 7714
Bao, SS,Otsubo, K,Taylor, JM,et al. Enhancing Proton Conduction in 2D Co-La Coordination Frameworks by Solid-State Phase Transition[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2014,136(26):9292—9295.
APA Bao, SS.,Otsubo, K.,Taylor, JM.,Jiang, Z.,Zheng, LM.,...&kitagawa@kuchem.kyoto-u.ac.jp.(2014).Enhancing Proton Conduction in 2D Co-La Coordination Frameworks by Solid-State Phase Transition.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,136(26),9292—9295.
MLA Bao, SS,et al."Enhancing Proton Conduction in 2D Co-La Coordination Frameworks by Solid-State Phase Transition".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 136.26(2014):9292—9295.
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