CAS OpenIR  > 中科院上海应用物理研究所2011-2019年
Highly selective hydrogenation of phenol and derivatives over Pd catalysts supported on SiO2 and gamma-Al2O3 in aqueous media
Cheng, L; Dai, QG; Li, H; Wang, XY; wangxy@ecust.edu.cn
2014
Source PublicationCATALYSIS COMMUNICATIONS
ISSN1566-7367
Volume57Pages:23—28
AbstractPd/Al2O3 and Pd/SiO2 catalysts containing Pd nanoparticles in the size range of 3-13 nm were prepared and investigated in direct selective hydrogenation of phenol to cyclohexanone. Catalysts with 3 nm Pd nanoparticles present highly active and promoted the selective formation of cyclohexanone under atmospheric pressure of hydrogen in aqueous media without additives. Conversion of 99% and a selectivity higher than 99% were achieved within 3 h at 333 K. The generality of Pd/Al2O3 catalyst with 3 nm Pd nanoparticles for this reaction was demonstrated by selective hydrogenation of other hydroxylated aromatic compounds with similar performance. (C) 2014 Published by Elsevier B.V.
KeywordVapor-phase Hydrogenation Palladium Catalysts Cyclohexanone Pressure Carbon
Indexed BySCI
Language英语
WOS IDWOS:000343364200006
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/14173
Collection中科院上海应用物理研究所2011-2019年
Corresponding Authorwangxy@ecust.edu.cn
Recommended Citation
GB/T 7714
Cheng, L,Dai, QG,Li, H,et al. Highly selective hydrogenation of phenol and derivatives over Pd catalysts supported on SiO2 and gamma-Al2O3 in aqueous media[J]. CATALYSIS COMMUNICATIONS,2014,57:23—28.
APA Cheng, L,Dai, QG,Li, H,Wang, XY,&wangxy@ecust.edu.cn.(2014).Highly selective hydrogenation of phenol and derivatives over Pd catalysts supported on SiO2 and gamma-Al2O3 in aqueous media.CATALYSIS COMMUNICATIONS,57,23—28.
MLA Cheng, L,et al."Highly selective hydrogenation of phenol and derivatives over Pd catalysts supported on SiO2 and gamma-Al2O3 in aqueous media".CATALYSIS COMMUNICATIONS 57(2014):23—28.
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