Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Nitrogen-doped graphene supported Pd@PdO core-shell clusters for C-C coupling reactions | |
| Jiang, BJ; Song, SZ; Wang, JQ; Xie, Y; Chu, WY; Li, HF; Xu, H; Tian, CG; Fu, HG; fuhg@vip.sina.com | |
| 2014 | |
| Source Publication | NANO RESEARCH
 |
| ISSN | 1998-0124 |
| Volume | 7Issue:9Pages:1280—1290 |
| Abstract | The introduction of nitrogen significantly decreases the metal particle size and improves the performance of metal-based graphene-supported catalysts. In this work, the density functional theory is used to understand the interaction between nitrogen-doped graphene and Pd@PdO clusters. Experiments show that small size Pd@PdO clusters (1-2 nm) can be grown uniformly on nitrogen-doped graphene sheets by a facile oxidation-reduction method. The nanoscale interaction relationship between nitrogen-doped graphene and Pd@PdO clusters is investigated through X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectra (XAS). The composite catalysts are applied in Suzuki-Miyaura reactions giving high yields and good structural stability. These results have potential impact in design and optimization of future high performance catalyst materials for cross coupling reactions. |
| Keyword | Enhanced Photocatalytic Activity Ray-absorption Spectroscopy Palladium Nanoparticles Graphite Oxide Catalyst Fabrication Reduction Resonance Facets Growth |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000342080100005 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/14274 |
| Collection | 中科院上海应用物理研究所2011-2019年 |
| Corresponding Author | fuhg@vip.sina.com |
| Recommended Citation GB/T 7714 | Jiang, BJ,Song, SZ,Wang, JQ,et al. Nitrogen-doped graphene supported Pd@PdO core-shell clusters for C-C coupling reactions[J]. NANO RESEARCH,2014,7(9):1280—1290. |
| APA | Jiang, BJ.,Song, SZ.,Wang, JQ.,Xie, Y.,Chu, WY.,...&fuhg@vip.sina.com.(2014).Nitrogen-doped graphene supported Pd@PdO core-shell clusters for C-C coupling reactions.NANO RESEARCH,7(9),1280—1290. |
| MLA | Jiang, BJ,et al."Nitrogen-doped graphene supported Pd@PdO core-shell clusters for C-C coupling reactions".NANO RESEARCH 7.9(2014):1280—1290. |
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| File Name/Size | DocType | Version | Access | License | ||
| Nitrogen-doped graph（2071KB） | 开放获取 | CC BY-NC-SA | View Download | |||
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