Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Photochemically Engineering the Metal-Semiconductor Interface for Room-Temperature Transfer Hydrogenation of Nitroarenes with Formic Acid | |
| Li, XH; Cai, YY; Gong, LH; Fu, W; Wang, KX; Bao, HL; Wei, X; Chen, JS; weixiao@sjtu.edu.cn; chemcj@sjtu.edu.cn | |
| 2014 | |
| Source Publication | CHEMISTRY-A EUROPEAN JOURNAL
 |
| ISSN | 0947-6539 |
| Volume | 20Issue:50Pages:16732—16737 |
| Abstract | A mild photochemical approach was applied to construct highly coupled metal-semiconductor dyads, which were found to efficiently facilitate the hydrogenation of nitrobenzene. Aniline was produced in excellent yield (>99 %, TOF: 1183) using formic acid as hydrogen source and water as solvent at room temperature. This general and green catalytic process is applicable to a wide range of nitroarenes without the involvement of high-pressure gases or sacrificial additives. |
| Keyword | Aromatic Nitro-compounds Catalytic-reduction Ambient Conditions Tandem Catalysis Gold Catalysts Efficient Nanoparticles Decomposition Generation Supports |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000346055800041 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/14310 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Corresponding Author | weixiao@sjtu.edu.cn; chemcj@sjtu.edu.cn |
| Recommended Citation GB/T 7714 | Li, XH,Cai, YY,Gong, LH,et al. Photochemically Engineering the Metal-Semiconductor Interface for Room-Temperature Transfer Hydrogenation of Nitroarenes with Formic Acid[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(50):16732—16737. |
| APA | Li, XH.,Cai, YY.,Gong, LH.,Fu, W.,Wang, KX.,...&chemcj@sjtu.edu.cn.(2014).Photochemically Engineering the Metal-Semiconductor Interface for Room-Temperature Transfer Hydrogenation of Nitroarenes with Formic Acid.CHEMISTRY-A EUROPEAN JOURNAL,20(50),16732—16737. |
| MLA | Li, XH,et al."Photochemically Engineering the Metal-Semiconductor Interface for Room-Temperature Transfer Hydrogenation of Nitroarenes with Formic Acid".CHEMISTRY-A EUROPEAN JOURNAL 20.50(2014):16732—16737. |
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| Photochemically Engi（584KB） | 开放获取 | CC BY-NC-SA | View Download | |||
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