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Reversible State Transition in Nanoconfined Aqueous Solutions | |
Zhao, L; Wang, CL; Liu, J; Wen, BH; Tu, YS; Wang, ZW; Fang, HP; wangchunlei@sinap.ac.cn; fanghaiping@sinap.ac.cn | |
2014 | |
Source Publication | PHYSICAL REVIEW LETTERS
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ISSN | 0031-9007 |
Volume | 112Issue:7 |
Abstract | Using molecular dynamics simulations, we find a reversible transition between the dispersion and aggregation states of solute molecules in aqueous solutions confined in nanoscale geometry, which is not observed in macroscopic systems. The nanoscale confinement also leads to a significant increase of the critical aggregation concentration (CAC). A theoretical model based on Gibbs free energy calculation is developed to describe the simulation results. It indicates that the reversible state transition is attributed to the low free energy barrier (of order k(B)T) in between two energy minima corresponding to the dispersion and aggregation states, and the enhancement of the CAC results from the fact that at lower concentrations the number of solute molecules is not large enough to allow the formation of a stable cluster in the confined systems. |
Keyword | Carbon Nanotubes Water Nanoparticles Aggregation Hydrophobicity Simulations Clusters Length |
Indexed By | SCI |
Language | 英语 |
WOS ID | WOS:000331953300035 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/14366 |
Collection | 中科院上海应用物理研究所2011-2020年 |
Corresponding Author | wangchunlei@sinap.ac.cn; fanghaiping@sinap.ac.cn |
Recommended Citation GB/T 7714 | Zhao, L,Wang, CL,Liu, J,et al. Reversible State Transition in Nanoconfined Aqueous Solutions[J]. PHYSICAL REVIEW LETTERS,2014,112(7). |
APA | Zhao, L.,Wang, CL.,Liu, J.,Wen, BH.,Tu, YS.,...&fanghaiping@sinap.ac.cn.(2014).Reversible State Transition in Nanoconfined Aqueous Solutions.PHYSICAL REVIEW LETTERS,112(7). |
MLA | Zhao, L,et al."Reversible State Transition in Nanoconfined Aqueous Solutions".PHYSICAL REVIEW LETTERS 112.7(2014). |
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