Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Solvent Influence on the Role of Thiols in Growth of Thiols-Capped Au Nanocrystals | |
| Jiang, Y; Huang, YY; Cheng, H; Liu, QH; Xie, Z; Yao, T; Jiang, Z; Bian, Q; Pan, GQ; Sun, ZH; Wei, SQ; yaot@ustc.edu.cn; zhsun@ustc.edu.cn | |
| 2014 | |
| Source Publication | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| ISSN | 1932-7447 |
| Volume | 118Issue:1Pages:714—719 |
| Abstract | Solvent has a key role in the controllable synthesis of nanocrystals (NCs). Here, using X-ray absorption spectroscopy, we demonstrate that solvent can significantly influence the adsorption of thiols on Au NCs, and thereby affects their growth. It is shown that increasing the solvent polarities leads to the higher thiol coverage on the NC surface. The high coverage of thiols then retards the growth of particles, and as a result, the NCs' sizes decrease with the increase in the solvents' polarities. The underlying reason for the solvent dependence is proposed to be the synergistic effects of different hydrogen bond and hydrophobic interactions between the sulfhydryl and alkyl groups of thiols with the solvents molecules. This work addresses the important role of the solvent environments in the size-controlled synthesis of NCs. |
| Keyword | Gold Nanoparticles Size Control Clusters Ligands Adsorption Nucleation Chemistry Phase |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000329678200079 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/14403 |
| Collection | 中科院上海应用物理研究所2011-2019年 |
| Corresponding Author | yaot@ustc.edu.cn; zhsun@ustc.edu.cn |
| Recommended Citation GB/T 7714 | Jiang, Y,Huang, YY,Cheng, H,et al. Solvent Influence on the Role of Thiols in Growth of Thiols-Capped Au Nanocrystals[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2014,118(1):714—719. |
| APA | Jiang, Y.,Huang, YY.,Cheng, H.,Liu, QH.,Xie, Z.,...&zhsun@ustc.edu.cn.(2014).Solvent Influence on the Role of Thiols in Growth of Thiols-Capped Au Nanocrystals.JOURNAL OF PHYSICAL CHEMISTRY C,118(1),714—719. |
| MLA | Jiang, Y,et al."Solvent Influence on the Role of Thiols in Growth of Thiols-Capped Au Nanocrystals".JOURNAL OF PHYSICAL CHEMISTRY C 118.1(2014):714—719. |
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