Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| A Study on the Degree of Amidoximation of Polyacrylonitrile Fibers and Its Effect on Their Capacity to Adsorb Uranyl Ions | |
| Zhao, HH; Liu, XY; Yu, M; Wang, ZQ; Zhang, BW; Ma, HJ; Wang, M; Li, JY | |
| 2015 | |
| Source Publication | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| Volume | 54Issue:12Pages:3101—3106 |
| Subtype | 期刊文献 |
| Abstract | Aroidoximation of polyacrylonitrile (PAN) fibers was studied by reacting them with hydroxylamine. The chemical structure, mechanical intensity, and morphologies of PAN and amidoximated PAN (AO PAN) fibers were evaluated by Fourier transform infrared spectroscopy, tensile tests, dynamic mechanical analysis, and scanning electron microscopy, respectively. A higher degree of amidOximation resulted in a higher conversion ratio (CR) of the nitrile group and a higher density of the. arnidoxithe group, while also reducing the mechanical intensity of the fibers. During amidoxirnation, a hydrogel layer formed on the fiber surface by bonding with H20 molecules, increasing the diameter of the AO-PAN fibers. The layer thickness increased as the CR of the AO-PAN fibers' oitrile group was increased. The hydrogel layer decreased the adsorption capability by hindering the diffilsion of uranyl ions to the interior of the AO-PAN fibers. Therefore, a CR of about 10.8% would provide an.appropriate balance between the mechanical properties and the adsorption capability. |
| Keyword | Metal-ions Sea-water Chelating Resins Uranium Seawater Recovery Adsorption Extraction Radiation Sorbers |
| Indexed By | SCI |
| Language | 英语 |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/24388 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Recommended Citation GB/T 7714 | Zhao, HH,Liu, XY,Yu, M,et al. A Study on the Degree of Amidoximation of Polyacrylonitrile Fibers and Its Effect on Their Capacity to Adsorb Uranyl Ions[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2015,54(12):3101—3106. |
| APA | Zhao, HH.,Liu, XY.,Yu, M.,Wang, ZQ.,Zhang, BW.,...&Li, JY.(2015).A Study on the Degree of Amidoximation of Polyacrylonitrile Fibers and Its Effect on Their Capacity to Adsorb Uranyl Ions.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,54(12),3101—3106. |
| MLA | Zhao, HH,et al."A Study on the Degree of Amidoximation of Polyacrylonitrile Fibers and Its Effect on Their Capacity to Adsorb Uranyl Ions".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 54.12(2015):3101—3106. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| A Study on the Degre（3568KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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