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| Conformation-Selective Resonant Photoelectron Spectroscopy via Dipole-Bound States of Cold Anions | |
| Huang, DL; Liu, HT; Ning, CG; Wang, LS | |
| 2015 | |
| Source Publication | JOURNAL OF PHYSICAL CHEMISTRY LETTERS
 |
| Volume | 6Issue:12Pages:2153—2157 |
| Subtype | 期刊文献 |
| Abstract | Molecular conformation is important in chemistry and biochemistry. Conformers connected by low energy barriers can only be observed at low temperatures and are difficult to be separated. Here we report a new method to obtain conformation-selective spectroscopic information about dipolar molecular radicals via dipole-bound excited states of the corresponding anions cooled in a cryogenic ion trap. We observed two conformers of cold 3-hydroxyphenoxide anions [m center dot HO(C6H4)O-] in high-resolution photoelectron spectroscopy and measured different electron affinities, 18 850(8) and 18 917(5) cm(-1), for the syn and anti 3-hydroxyphenoxy radicals, respectively. We also observed dipole-bound excited states for m-HO(C6H4)O- with different binding energies for the two conformers due to the different dipole moments of the corresponding 3-hydroxyphenoxy radicals. Excitations to selected vibrational levels of the dipole-bound states result in conformation-selective photoelectron spectra. This method should be applicable to conformation-selective spectroscopic studies of any anions with dipolar neutral cores. |
| Keyword | Gas-phase Vibrational Spectroscopy Ground-state Electron Ions Photodetachment Autodetachment Isomerization Ionization System |
| Indexed By | SCI |
| Language | 英语 |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/24416 |
| Collection | 中科院上海应用物理研究所2011-2019年 |
| Recommended Citation GB/T 7714 | Huang, DL,Liu, HT,Ning, CG,et al. Conformation-Selective Resonant Photoelectron Spectroscopy via Dipole-Bound States of Cold Anions[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS,2015,6(12):2153—2157. |
| APA | Huang, DL,Liu, HT,Ning, CG,&Wang, LS.(2015).Conformation-Selective Resonant Photoelectron Spectroscopy via Dipole-Bound States of Cold Anions.JOURNAL OF PHYSICAL CHEMISTRY LETTERS,6(12),2153—2157. |
| MLA | Huang, DL,et al."Conformation-Selective Resonant Photoelectron Spectroscopy via Dipole-Bound States of Cold Anions".JOURNAL OF PHYSICAL CHEMISTRY LETTERS 6.12(2015):2153—2157. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Conformation-Selecti（1760KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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