CAS OpenIR  > 中科院上海应用物理研究所2011-2019年
Infrared spectroscopic and theoretical study of the reactions of cerium atoms with methanol in solid argon
Li, YZ; Gong, Y; Zhou, XJ; Su, J; Li, J; Zhou, MF
2015
Source PublicationJOURNAL OF MOLECULAR SPECTROSCOPY
Volume310Pages:50—56
Subtype期刊文献
AbstractReactions of cerium metal atoms with methanol are investigated using matrix isolation infrared absorption spectroscopy and density functional theoretical calculations. Upon reaction of the ground state cerium metal atoms with methanol, the insertion intermediate CH3OCeH is formed spontaneously on annealing in solid argon. Further sample annealing allows the reaction of CH3OCeH with another methanol molecule to form H-2 and Ce(OCH3)(2). The divalent Ce(OCH3)(2) molecule can further isomerize to the more stable tetravalent CH3OCe(O)CH3 isomer under UV-visible irradiation. The product species are identified via isotopic substitutions and vibrational frequency calculations. (C) 2014 Elsevier Inc. All rights reserved.
KeywordLanthanide Metal Atoms Gas-phase Reactions Room-temperature Kinetics Matrix-isolation Reaction-products Ground-state La-lu Density Cations Spectra
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/24478
Collection中科院上海应用物理研究所2011-2019年
Recommended Citation
GB/T 7714
Li, YZ,Gong, Y,Zhou, XJ,et al. Infrared spectroscopic and theoretical study of the reactions of cerium atoms with methanol in solid argon[J]. JOURNAL OF MOLECULAR SPECTROSCOPY,2015,310:50—56.
APA Li, YZ,Gong, Y,Zhou, XJ,Su, J,Li, J,&Zhou, MF.(2015).Infrared spectroscopic and theoretical study of the reactions of cerium atoms with methanol in solid argon.JOURNAL OF MOLECULAR SPECTROSCOPY,310,50—56.
MLA Li, YZ,et al."Infrared spectroscopic and theoretical study of the reactions of cerium atoms with methanol in solid argon".JOURNAL OF MOLECULAR SPECTROSCOPY 310(2015):50—56.
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