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Solvothermal synthesis, structures, and magnetic properties of Ni-II compounds directed by N,N '-bridging auxiliary ligands
Zhang, N; Sun, YJ; Yang, H; Zhang, JY; Gao, EQ
2015
Source PublicationINORGANICA CHIMICA ACTA
Volume428Pages:37—43
Subtype期刊文献
AbstractThree Ni(II-)based metal-organic frameworks (MOFs) were synthesized from the nitro-functionalized dicarboxylate ligand 2,2'-dinitro-biphenyl-4,4'-dicarboxylate (H(2)dnpdc) and different N-donor bridging ligands. X-ray analyses revealed that all compounds exhibit 3D architectures. Compound 1, {Ni(dnpdc)(bipy)}(n), exhibits 3D framework in which the 2D Ni(dnpdc) sheets are pillared by bipy, with a new (4,6)-connected self-penetrated net topology. In compound 2, {[Ni-3(dnpdc)(3)(bipy)(3)(H2O)(2)]center dot(H2O)(2)}(n), the binuclear Ni-2(COO)(2) units and mononuclear units are interlinked by the dnpdc and bipy ligands into 3D framework, which displays a rare 3-fold interpenetrated (4,6)-connected net topology. Compound 3, {Ni(dnpdc)(bpee)center dot H2O}(n), displays a 6-fold interpenetrated diamond net based on the mononuclear Ni-II unit. The magnetic studies of 1 reveal that the double carboxylate bridges in the nonplanar syn-skew conformation mediate ferromagnetic interactions between the NiII ions. (C) 2015 Elsevier B.V. All rights reserved.
KeywordMetal-organic Frameworks Complexes Construction 2 Temperature 2'-dinitrobiphenyl-4 1d 4'-dicarboxylate
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/24571
Collection中科院上海应用物理研究所2011-2020年
Recommended Citation
GB/T 7714
Zhang, N,Sun, YJ,Yang, H,et al. Solvothermal synthesis, structures, and magnetic properties of Ni-II compounds directed by N,N '-bridging auxiliary ligands[J]. INORGANICA CHIMICA ACTA,2015,428:37—43.
APA Zhang, N,Sun, YJ,Yang, H,Zhang, JY,&Gao, EQ.(2015).Solvothermal synthesis, structures, and magnetic properties of Ni-II compounds directed by N,N '-bridging auxiliary ligands.INORGANICA CHIMICA ACTA,428,37—43.
MLA Zhang, N,et al."Solvothermal synthesis, structures, and magnetic properties of Ni-II compounds directed by N,N '-bridging auxiliary ligands".INORGANICA CHIMICA ACTA 428(2015):37—43.
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