Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| A Near-Infrared-Emissive Alkynyl-Protected Au-24 Nanocluster | |
| Wan, XK; Xu, WW; Yuan, SF; Gao, Y; Zeng, XC; Wang, QM; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China. | |
| 2015 | |
| Source Publication | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| ISSN | 1433-7851 |
| Volume | 54Issue:33Pages:9683—9686 |
| Subtype | 期刊文献 |
| Abstract | An alkynyl-protected gold nanocluster [Au-24(CCPh)(14)(PPh3)(4)](SbF6)(2) has been prepared by a direct reduction method. Single-crystal X-ray diffraction reveals that the molecular structure contains a Au(22)core that is made of two Au-13-centered cuboctahedra that share a square face. Two staple-like PhCCAuCCPh motifs are located around the center of the rod-like Au(22)core. This Au-24 nanocluster is highly emissive in the near-infrared region with (max)=925nm and the nature of the HOMO-LUMO transition is investigated by time-dependent DFT calculations. |
| Keyword | Gold Clusters Optical-properties Crystal-structure Structural Evolution Theoretical-analysis Superatom Complexes Nanoparticles Motif Au-18(Sr)(14) System |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000358987300045 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/24853 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Corresponding Author | Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China. |
| Recommended Citation GB/T 7714 | Wan, XK,Xu, WW,Yuan, SF,et al. A Near-Infrared-Emissive Alkynyl-Protected Au-24 Nanocluster[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2015,54(33):9683—9686. |
| APA | Wan, XK.,Xu, WW.,Yuan, SF.,Gao, Y.,Zeng, XC.,...&Gao, Y .(2015).A Near-Infrared-Emissive Alkynyl-Protected Au-24 Nanocluster.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,54(33),9683—9686. |
| MLA | Wan, XK,et al."A Near-Infrared-Emissive Alkynyl-Protected Au-24 Nanocluster".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 54.33(2015):9683—9686. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| A Near-Infrared-Emis（2215KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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