CAS OpenIR  > 中科院上海应用物理研究所2011-2019年
Bio-inspired Construction of Advanced Fuel Cell Cathode with Pt Anchored in Ordered Hybrid Polymer Matrix
Xia, ZX; Wang, SL; Jiang, LH; Sun, H; Liu, S; Fu, XD; Zhang, BS; Su, DS; Wang, JQ; Sun, GQ; Sun, GQ (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Fuel Cell & Battery, Dalian 116023, Peoples R China.
2015
Source PublicationSCIENTIFIC REPORTS
ISSN2045-2322
Volume5Pages:
Subtype期刊文献
AbstractThe significant use of platinum for catalyzing the cathodic oxygen reduction reactions (ORRs) has hampered the widespread use of polymer electrolyte membrane fuel cells (PEMFCs). The construction of well-defined electrode architecture in nanoscale with enhanced utilization and catalytic performance of Pt might be a promising approach to address such barrier. Inspired by the highly efficient catalytic processes in enzymes with active centers embedded in charge transport pathways, here we demonstrate for the first time a design that allocates platinum nanoparticles (Pt NPs) at the boundaries with dual-functions of conducting both electrons by aid of polypyrrole and protons via Nafion (R) ionomer within hierarchical nanoarrays. By mimicking enzymes functionally, an impressive ORR activity and stability is achieved. Using this brand new electrode architecture as the cathode and the anode of a PEMFC, a high mass specific power density of 5.23 W mg(Pt)(-1) is achieved, with remarkable durability. These improvements are ascribed to not only the electron decoration and the anchoring effects from the Nafion r ionomer decorated PPy substrate to the supported Pt NPs, but also the fast charge and mass transport facilitated by the electron and proton pathways within the electrode architecture.
KeywordOxygen Reduction Reaction Electrocatalysts Polypyrrole Catalysts Membrane Platinum Carbon Challenges Electrodes Stability
Indexed BySCI
Language英语
WOS IDWOS:000364134800002
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Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/24873
Collection中科院上海应用物理研究所2011-2019年
Corresponding AuthorSun, GQ (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Fuel Cell & Battery, Dalian 116023, Peoples R China.
Recommended Citation
GB/T 7714
Xia, ZX,Wang, SL,Jiang, LH,et al. Bio-inspired Construction of Advanced Fuel Cell Cathode with Pt Anchored in Ordered Hybrid Polymer Matrix[J]. SCIENTIFIC REPORTS,2015,5:—.
APA Xia, ZX.,Wang, SL.,Jiang, LH.,Sun, H.,Liu, S.,...&Sun, GQ .(2015).Bio-inspired Construction of Advanced Fuel Cell Cathode with Pt Anchored in Ordered Hybrid Polymer Matrix.SCIENTIFIC REPORTS,5,—.
MLA Xia, ZX,et al."Bio-inspired Construction of Advanced Fuel Cell Cathode with Pt Anchored in Ordered Hybrid Polymer Matrix".SCIENTIFIC REPORTS 5(2015):—.
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