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| Electrochemical investigation of the stable chromium species in molten FLINAK | |
| Peng, H; Shen, M; Wang, CY; Su, T; Zuo, Y; Xie, LD; Xie, LD (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China. | |
| 2015 | |
| Source Publication | RSC ADVANCES
 |
| ISSN | 2046-2069 |
| Volume | 5Issue:94Pages:76689—76695 |
| Subtype | 期刊文献 |
| Abstract | The electrochemical behavior of Cr(III) in FLINAK melts at 600 degrees C was studied through cyclic voltammetry (CV) and square wave voltammetry (SWV). Cr(III) reduction proceeded in two steps: initial Cr(III) reduction to Cr(II) followed by subsequent reduction to Cr. The peak corresponding to the reduction of Cr(III) to Cr(II) was also observed in SWVs and CVs even though only CrF2 was added to the FLINAK melts. This result confirms that Cr(II) was converted to Cr(III) via disproportion: 3Cr(II) = 2Cr(III) + Cr. Such a conversion could be attributed to the formation of the stable species [CrF6](3-), as determined through Raman spectroscopy. |
| Keyword | Square Wave Voltammetry Oxide Ions Nuclear Applications Reactive Electrodes Hydrogen Fluoride Salt Corrosion Lif-caf2 Thorium Inert |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000361559700004 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/24914 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Corresponding Author | Xie, LD (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China. |
| Recommended Citation GB/T 7714 | Peng, H,Shen, M,Wang, CY,et al. Electrochemical investigation of the stable chromium species in molten FLINAK[J]. RSC ADVANCES,2015,5(94):76689—76695. |
| APA | Peng, H.,Shen, M.,Wang, CY.,Su, T.,Zuo, Y.,...&Xie, LD .(2015).Electrochemical investigation of the stable chromium species in molten FLINAK.RSC ADVANCES,5(94),76689—76695. |
| MLA | Peng, H,et al."Electrochemical investigation of the stable chromium species in molten FLINAK".RSC ADVANCES 5.94(2015):76689—76695. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Electrochemical inve（1427KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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