Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation

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	Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation
	Ao, YY; Xu, M; Peng, J; Li, JQ; Zhai, ML; Wu, GZ; Ao, YY (reprint author), Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci Radiochem & Radiat Chem, Key Lab Fundamental Sci, Beijing 100871, Peoples R China.
	2015
发表期刊	NUCLEAR SCIENCE AND TECHNIQUES
ISSN	1001-8042
卷号	26 期号:3 页码:—
文章类型	期刊文献
摘要	The trace water-soluble radiolytic products of neat 1-butyl-3-methylimidazolium hexafluorophosphate ([C(4)mim][PF6]) were identified by analysing water-washed samples of gamma-irradiated ionic liquids. HF and difluorophosphinic acid were confirmed as the main radiolytic products of [C(4)mim][PF6], and their radiation chemical yields were quantified by F-19 NMR (G(F-) = 0.14 mu mol/J, G(HOP(O)F-2) = 0.053 mu mol/J). Compared to [C(4)mim][NTf2], [C(4)mim][PF6] shows better radiation stability.
关键词	Temperature Ionic Liquids Induced Redox Reactions Solvent-extraction Constituent Ions Strontium Ions Radiation Hexafluorophosphate Fragmentation Stability Anions
语种	英语
WOS记录号	WOS:000358109700009
引用统计
文献类型	期刊论文
条目标识符	http://ir.sinap.ac.cn/handle/331007/24948
专题	中科院上海应用物理研究所2011-2018年
通讯作者	Ao, YY (reprint author), Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci Radiochem & Radiat Chem, Key Lab Fundamental Sci, Beijing 100871, Peoples R China.
推荐引用方式 GB/T 7714	Ao, YY,Xu, M,Peng, J,et al. Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation[J]. NUCLEAR SCIENCE AND TECHNIQUES,2015,26(3):—.
APA	Ao, YY.,Xu, M.,Peng, J.,Li, JQ.,Zhai, ML.,...&Ao, YY .(2015).Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation.NUCLEAR SCIENCE AND TECHNIQUES,26(3),—.
MLA	Ao, YY,et al."Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation".NUCLEAR SCIENCE AND TECHNIQUES 26.3(2015):—.

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