Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation | |
| Ao, YY; Xu, M; Peng, J; Li, JQ; Zhai, ML; Wu, GZ; Ao, YY (reprint author), Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci Radiochem & Radiat Chem, Key Lab Fundamental Sci, Beijing 100871, Peoples R China. | |
| 2015 | |
| Source Publication | NUCLEAR SCIENCE AND TECHNIQUES
 |
| ISSN | 1001-8042 |
| Volume | 26Issue:3Pages:— |
| Subtype | 期刊文献 |
| Abstract | The trace water-soluble radiolytic products of neat 1-butyl-3-methylimidazolium hexafluorophosphate ([C(4)mim][PF6]) were identified by analysing water-washed samples of gamma-irradiated ionic liquids. HF and difluorophosphinic acid were confirmed as the main radiolytic products of [C(4)mim][PF6], and their radiation chemical yields were quantified by F-19 NMR (G(F-) = 0.14 mu mol/J, G(HOP(O)F-2) = 0.053 mu mol/J). Compared to [C(4)mim][NTf2], [C(4)mim][PF6] shows better radiation stability. |
| Keyword | Temperature Ionic Liquids Induced Redox Reactions Solvent-extraction Constituent Ions Strontium Ions Radiation Hexafluorophosphate Fragmentation Stability Anions |
| Language | 英语 |
| WOS ID | WOS:000358109700009 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/24948 |
| Collection | 中科院上海应用物理研究所2011-2019年 |
| Corresponding Author | Ao, YY (reprint author), Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci Radiochem & Radiat Chem, Key Lab Fundamental Sci, Beijing 100871, Peoples R China. |
| Recommended Citation GB/T 7714 | Ao, YY,Xu, M,Peng, J,et al. Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation[J]. NUCLEAR SCIENCE AND TECHNIQUES,2015,26(3):—. |
| APA | Ao, YY.,Xu, M.,Peng, J.,Li, JQ.,Zhai, ML.,...&Ao, YY .(2015).Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation.NUCLEAR SCIENCE AND TECHNIQUES,26(3),—. |
| MLA | Ao, YY,et al."Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation".NUCLEAR SCIENCE AND TECHNIQUES 26.3(2015):—. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Identification of ra（346KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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