Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation
Ao, YY; Xu, M; Peng, J; Li, JQ; Zhai, ML; Wu, GZ; Ao, YY (reprint author), Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci Radiochem & Radiat Chem, Key Lab Fundamental Sci, Beijing 100871, Peoples R China.
2015
发表期刊NUCLEAR SCIENCE AND TECHNIQUES
ISSN1001-8042
卷号26期号:3页码:
文章类型期刊文献
摘要The trace water-soluble radiolytic products of neat 1-butyl-3-methylimidazolium hexafluorophosphate ([C(4)mim][PF6]) were identified by analysing water-washed samples of gamma-irradiated ionic liquids. HF and difluorophosphinic acid were confirmed as the main radiolytic products of [C(4)mim][PF6], and their radiation chemical yields were quantified by F-19 NMR (G(F-) = 0.14 mu mol/J, G(HOP(O)F-2) = 0.053 mu mol/J). Compared to [C(4)mim][NTf2], [C(4)mim][PF6] shows better radiation stability.
关键词Temperature Ionic Liquids Induced Redox Reactions Solvent-extraction Constituent Ions Strontium Ions Radiation Hexafluorophosphate Fragmentation Stability Anions
语种英语
WOS记录号WOS:000358109700009
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被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/24948
专题中科院上海应用物理研究所2011-2018年
通讯作者Ao, YY (reprint author), Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci Radiochem & Radiat Chem, Key Lab Fundamental Sci, Beijing 100871, Peoples R China.
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Ao, YY,Xu, M,Peng, J,et al. Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation[J]. NUCLEAR SCIENCE AND TECHNIQUES,2015,26(3):—.
APA Ao, YY.,Xu, M.,Peng, J.,Li, JQ.,Zhai, ML.,...&Ao, YY .(2015).Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation.NUCLEAR SCIENCE AND TECHNIQUES,26(3),—.
MLA Ao, YY,et al."Identification of radiolytic products of [C(4)mim][PF6] under gamma-irradiation".NUCLEAR SCIENCE AND TECHNIQUES 26.3(2015):—.
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