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| In Situ XAFS Methods for Characterizing Catalyst Structure in Proton Exchange Membrane Fuel Cell | |
| Shang, MF; Duan, PQ; Zhao, TT; Tang, WC; Lin, R; Huang, YY; Wang, JQ; Huang, YY (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China. | |
| 2015 | |
| Source Publication | ACTA PHYSICO-CHIMICA SINICA
 |
| ISSN | 1000-6818 |
| Volume | 31Issue:8Pages:1609—1614 |
| Subtype | 期刊文献 |
| Abstract | We established and developed an in situ X-ray absorption fine structure (XAFS) experimental testing device for characterizing hydrogen-oxygen proton exchange membrane fuel cells (PEMFC) on XAFS beamline BL14W1 at the Shanghai Synchrotron Radiation Facility (SSRF). XAFS data were collected under the operating state of the fuel cell with Pt/C and Pd/C as the cathode and anode catalysts, respectively, while the cell current-voltage (J-V) Curve and power density curves were monitored. Changes in the oxidation states of the Pt/C catalyst were observed during the reaction process at different potentials. Strong Pt-O bonds on the surfaces of the Pt were found to be induced at high potential; this may hinder the performance of Pt and reduce its oxygen reduction reaction (ORR) activity. The study also verified the reliability and feasibility of the herein established experimental apparatus and technique. |
| Keyword | Ray-absorption Spectroscopy Ru Anode Electrocatalyst Platinum-electrodes Methanol Oxidation Ftir Spectroscopy Oxygen Reduction Adsorption Reformate |
| Language | 英语 |
| WOS ID | WOS:000361118400022 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/24959 |
| Collection | 中科院上海应用物理研究所2011-2018年 |
| Corresponding Author | Huang, YY (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China. |
| Recommended Citation GB/T 7714 | Shang, MF,Duan, PQ,Zhao, TT,et al. In Situ XAFS Methods for Characterizing Catalyst Structure in Proton Exchange Membrane Fuel Cell[J]. ACTA PHYSICO-CHIMICA SINICA,2015,31(8):1609—1614. |
| APA | Shang, MF.,Duan, PQ.,Zhao, TT.,Tang, WC.,Lin, R.,...&Huang, YY .(2015).In Situ XAFS Methods for Characterizing Catalyst Structure in Proton Exchange Membrane Fuel Cell.ACTA PHYSICO-CHIMICA SINICA,31(8),1609—1614. |
| MLA | Shang, MF,et al."In Situ XAFS Methods for Characterizing Catalyst Structure in Proton Exchange Membrane Fuel Cell".ACTA PHYSICO-CHIMICA SINICA 31.8(2015):1609—1614. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| In Situ XAFS Methods（12219KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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