In Situ X-ray Diffraction Study of Co-Al Nanocomposites as Catalysts for Ammonia Decomposition

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	In Situ X-ray Diffraction Study of Co-Al Nanocomposites as Catalysts for Ammonia Decomposition
	Gu, YQ; Fu, XP; Du, PP; Gu, D; Jin, Z; Huang, YY; Si, R; Zheng, LQ; Song, QS; Jia, CJ; Weidenthaler, C; Si, R (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China.
	2015
发表期刊	JOURNAL OF PHYSICAL CHEMISTRY C
ISSN	1932-7447
卷号	119 期号:30 页码:17102—17110
文章类型	期刊文献
摘要	Co-Al nanocomposite material's as active and stable catalysts for ammonia decomposition have been synthesized by a one-pot evaporation-induced self-assembly method: The catalysts were characterized by various techniques including powder X-ray diffraction (XRD), X-ray absorption fine structure (XAFS), X-ray photoelectron spectroscopy (XPS), N-2 adsorption/desorption, and -transmission/scanning electron microscopy (TEM/SEM). Especially, in situ XRD under Catalytic reaction conditions was performed and metallic Co with a cubic structure was identified to be most probably the active, crystalline phase for the decomposition of ammonia; also, contribution of CoO to the catalytic activity cannot be excluded. Most importantly, the introduction of alumina an significantly suppress the agglomeration of the active metallic Co phase and thus maintain the high activity of the cobalt catalyst.
关键词	Fuel-cell Applications Nh3 Decomposition Free Hydrogen Carbon Nanotubes Size Nanoparticles Generation Oxidation Behavior
语种	英语
WOS记录号	WOS:000359031900009
引用统计	被引频次：9[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.sinap.ac.cn/handle/331007/24960
专题	中科院上海应用物理研究所2011-2018年
通讯作者	Si, R (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China.
推荐引用方式 GB/T 7714	Gu, YQ,Fu, XP,Du, PP,et al. In Situ X-ray Diffraction Study of Co-Al Nanocomposites as Catalysts for Ammonia Decomposition[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2015,119(30):17102—17110.
APA	Gu, YQ.,Fu, XP.,Du, PP.,Gu, D.,Jin, Z.,...&Si, R .(2015).In Situ X-ray Diffraction Study of Co-Al Nanocomposites as Catalysts for Ammonia Decomposition.JOURNAL OF PHYSICAL CHEMISTRY C,119(30),17102—17110.
MLA	Gu, YQ,et al."In Situ X-ray Diffraction Study of Co-Al Nanocomposites as Catalysts for Ammonia Decomposition".JOURNAL OF PHYSICAL CHEMISTRY C 119.30(2015):17102—17110.

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