In Situ X-ray Diffraction Study of Co-Al Nanocomposites as Catalysts for Ammonia Decomposition

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	In Situ X-ray Diffraction Study of Co-Al Nanocomposites as Catalysts for Ammonia Decomposition
	Gu, YQ; Fu, XP; Du, PP; Gu, D; Jin, Z; Huang, YY; Si, R; Zheng, LQ; Song, QS; Jia, CJ; Weidenthaler, C; Si, R (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China.
	2015
Source Publication	JOURNAL OF PHYSICAL CHEMISTRY C
ISSN	1932-7447
Volume	119 Issue:30 Pages:17102—17110
Subtype	期刊文献
Abstract	Co-Al nanocomposite material's as active and stable catalysts for ammonia decomposition have been synthesized by a one-pot evaporation-induced self-assembly method: The catalysts were characterized by various techniques including powder X-ray diffraction (XRD), X-ray absorption fine structure (XAFS), X-ray photoelectron spectroscopy (XPS), N-2 adsorption/desorption, and -transmission/scanning electron microscopy (TEM/SEM). Especially, in situ XRD under Catalytic reaction conditions was performed and metallic Co with a cubic structure was identified to be most probably the active, crystalline phase for the decomposition of ammonia; also, contribution of CoO to the catalytic activity cannot be excluded. Most importantly, the introduction of alumina an significantly suppress the agglomeration of the active metallic Co phase and thus maintain the high activity of the cobalt catalyst.
Keyword	Fuel-cell Applications Nh3 Decomposition Free Hydrogen Carbon Nanotubes Size Nanoparticles Generation Oxidation Behavior
Language	英语
WOS ID	WOS:000359031900009
Citation statistics	Cited Times:11[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.sinap.ac.cn/handle/331007/24960
Collection	中科院上海应用物理研究所2011-2019年
Corresponding Author	Si, R (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China.
Recommended Citation GB/T 7714	Gu, YQ,Fu, XP,Du, PP,et al. In Situ X-ray Diffraction Study of Co-Al Nanocomposites as Catalysts for Ammonia Decomposition[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2015,119(30):17102—17110.
APA	Gu, YQ.,Fu, XP.,Du, PP.,Gu, D.,Jin, Z.,...&Si, R .(2015).In Situ X-ray Diffraction Study of Co-Al Nanocomposites as Catalysts for Ammonia Decomposition.JOURNAL OF PHYSICAL CHEMISTRY C,119(30),17102—17110.
MLA	Gu, YQ,et al."In Situ X-ray Diffraction Study of Co-Al Nanocomposites as Catalysts for Ammonia Decomposition".JOURNAL OF PHYSICAL CHEMISTRY C 119.30(2015):17102—17110.

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