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Pressure-induced phase transition and dissociation of PbMoO4 | |
Huang, SX; Lai, XJ; Zhu, F; Wu, X; Yang, K; Qin, S; Wu, X (reprint author), Peking Univ, MOE, Key Lab Orogen Belts & Crustal Evolut, Beijing 100871, Peoples R China. | |
2015 | |
Source Publication | PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS
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ISSN | 0370-1972 |
Volume | 252Issue:10Pages:2215—2221 |
Subtype | 期刊文献 |
Abstract | The high-pressure behavior of PbMoO4 has been studied by in situ synchrotron radiation X-ray diffraction (XRD) combined with a diamond anvil cell (DAC) up to approximate to 38GPa. At room temperature, phase transitions of PbMoO4 from the scheelite structure to the wolframite structure and then to amorphization are detected at approximate to 8.3 and approximate to 35GPa, respectively. Pressure-volume relationships of PbMoO4 are described by the Birch-Murnaghan equation of state, giving V-0=355.8(3)angstrom(3), K-0=73(4)GPa, K-0=5(1) (third order) for the scheelite-structured phase and V-0=166(1)angstrom(3), K-0=85(4)GPa, K-0=4 (fixed) (second order) for the wolframite-structured phase. When PbMoO4 undergoes the high-temperature annealing treatment at approximate to 17.5GPa, it will dissociate into assembly of the PbO (Pbcm and Z=4) and PbMo2O7 (P2(1)/c and Z=4). |
Keyword | X-ray-diffraction Eu Binary Oxides Crystal Stability Scheelite Awo(4) Pbwo4 Crystal Cawo4 Scintillators Raman Transformations Performance |
Language | 英语 |
WOS ID | WOS:000362722300010 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/25019 |
Collection | 中科院上海应用物理研究所2011-2020年 |
Corresponding Author | Wu, X (reprint author), Peking Univ, MOE, Key Lab Orogen Belts & Crustal Evolut, Beijing 100871, Peoples R China. |
Recommended Citation GB/T 7714 | Huang, SX,Lai, XJ,Zhu, F,et al. Pressure-induced phase transition and dissociation of PbMoO4[J]. PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS,2015,252(10):2215—2221. |
APA | Huang, SX.,Lai, XJ.,Zhu, F.,Wu, X.,Yang, K.,...&Wu, X .(2015).Pressure-induced phase transition and dissociation of PbMoO4.PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS,252(10),2215—2221. |
MLA | Huang, SX,et al."Pressure-induced phase transition and dissociation of PbMoO4".PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS 252.10(2015):2215—2221. |
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