Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Shape-Dependent Activity of Ceria for Hydrogen Electro-Oxidation in Reduced-Temperature Solid Oxide Fuel Cells | |
| Tong, XF; Luo, T; Meng, X; Wu, H; Li, JL; Liu, XJ; Ji, XN; Wang, JQ; Chen, CS; Zhan, ZL; Wang, JQ (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, 239 Zhangheng Rd, Shanghai 201204, Peoples R China. | |
| 2015 | |
| Source Publication | SMALL
 |
| ISSN | 1613-6810 |
| Volume | 11Issue:41Pages:5581—5588 |
| Subtype | 期刊文献 |
| Abstract | Single crystalline ceria nanooctahedra, nanocubes, and nanorods are hydrothermally synthesized, colloidally impregnated into the porous La0.9Sr0.1Ga0.8Mg0.2O3- (LSGM) scaffolds, and electrochemically evaluated as the anode catalysts for reduced temperature solid oxide fuel cells (SOFCs). Well-defined surface terminations are confirmed by the high-resolution transmission electron microscopy (111) for nanooctahedra, (100) for nanocubes, and both (110) and (100) for nanorods. Temperature-programmed reduction in H-2 shows the highest reducibility for nanorods, followed sequentially by nanocubes and nanooctahedra. Measurements of the anode polarization resistances and the fuel cell power densities reveal different orders of activity of ceria nanocrystals at high and low temperatures for hydrogen electro-oxidation, i.e., nanorods > nanocubes > nanooctahedra at T 450 degrees C and nanooctahedra > nanorods > nanocubes at T 500 degrees C. Such shape-dependent activities of these ceria nanocrystals have been correlated to their difference in the local structure distortions and thus in the reducibility. These findings will open up a new strategy for design of advanced catalysts for reduced-temperature SOFCs by elaborately engineering the shape of nanocrystals and thus selectively exposing the crystal facets. |
| Keyword | Defined Surface Planes Gas Shift Reaction Catalyzed Soot Oxidation Ceo2 Nanocrystals Co Oxidation Anode Materials Oxygen Storage Sofc Anodes Adsorption Nanorods |
| Language | 英语 |
| WOS ID | WOS:000363593600016 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/25038 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Corresponding Author | Wang, JQ (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, 239 Zhangheng Rd, Shanghai 201204, Peoples R China. |
| Recommended Citation GB/T 7714 | Tong, XF,Luo, T,Meng, X,et al. Shape-Dependent Activity of Ceria for Hydrogen Electro-Oxidation in Reduced-Temperature Solid Oxide Fuel Cells[J]. SMALL,2015,11(41):5581—5588. |
| APA | Tong, XF.,Luo, T.,Meng, X.,Wu, H.,Li, JL.,...&Wang, JQ .(2015).Shape-Dependent Activity of Ceria for Hydrogen Electro-Oxidation in Reduced-Temperature Solid Oxide Fuel Cells.SMALL,11(41),5581—5588. |
| MLA | Tong, XF,et al."Shape-Dependent Activity of Ceria for Hydrogen Electro-Oxidation in Reduced-Temperature Solid Oxide Fuel Cells".SMALL 11.41(2015):5581—5588. |
| Files in This Item: | Download All | |||||
| File Name/Size | DocType | Version | Access | License | ||
| Shape-Dependent Acti（1316KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment