Structure, Optical Absorption, and Performance of Organic Solar Cells Improved by Gold Nanoparticles in Buffer Layers

CAS OpenIR > 中科院上海应用物理研究所2011-2020年

	Structure, Optical Absorption, and Performance of Organic Solar Cells Improved by Gold Nanoparticles in Buffer Layers
	Yang, YG; Feng, SL; Li, M; Wu, ZW; Fang, X; Wang, F; Geng, DP; Yang, TY; Li, XL; Sun, BQ; Gao, XY; Sun, BQ (reprint author), Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Inst Funct Nano & Soft Mat FUNSOM, 199 Renai Rd, Suzhou 215123, Peoples R China.
	2015
Source Publication	ACS APPLIED MATERIALS & INTERFACES
ISSN	1944-8244
Volume	7 Issue:44 Pages:24430—24437
Subtype	期刊文献
Abstract	11-Mercaptoundecanoic acid (MUM-stabilized gold nanoparticles (AuNPs) embedded in copper phthalocyanine (CuPc) were used as a buffer layer between a poly(3-hexyl-thiophene) (P3HT)/[6,6]-phenyl C61-butyric acid methyl ester (PCBM) bulk heterojunction and anodic indium-tin oxide (ITO) substrate. As systematic synchrotron-based grazing incidence X-ray diffraction (GIXRD) experiments demonstrated that the AuNPs present in the buffer layer can improve the microstructure of the active layer with a better lamella packing of P3HT from the surface to the interior, UV-visible absorption spectrum measurements revealed enhanced optical absorption due to the localized surface plasma resonance (LSPR) generated by the AuNPs. The device of ITO/poly(3,4-ethylenedioxythiophene) :polystyrenesulfonate/CuPc:MUA-stabilized AuNPs/P3HT:PCBM/LiF/Al was found with over 24% enhancement of power conversion efficiency (PCE) in comparison with reference devices without AuNPs. This remarkable improvement in PCE should be partially attributed to LSPR generated by the AuNPs and partially to improved crystallization as well as preferred orientation order of P3HT due to the presence of the AuNPs, which would promote more applications of metal NPs in the organic photovoltaic devices and other organic multilayer devices.
Keyword	Self-organization Fill Factor Thin-films Polymer Fullerene Morphology Poly(3-hexylthiophene) Polythiophene Efficiency Blends
Language	英语
WOS ID	WOS:000364726400007
Citation statistics
Document Type	期刊论文
Identifier	http://ir.sinap.ac.cn/handle/331007/25052
Collection	中科院上海应用物理研究所2011-2020年
Corresponding Author	Sun, BQ (reprint author), Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Inst Funct Nano & Soft Mat FUNSOM, 199 Renai Rd, Suzhou 215123, Peoples R China.
Recommended Citation GB/T 7714	Yang, YG,Feng, SL,Li, M,et al. Structure, Optical Absorption, and Performance of Organic Solar Cells Improved by Gold Nanoparticles in Buffer Layers[J]. ACS APPLIED MATERIALS & INTERFACES,2015,7(44):24430—24437.
APA	Yang, YG.,Feng, SL.,Li, M.,Wu, ZW.,Fang, X.,...&Sun, BQ .(2015).Structure, Optical Absorption, and Performance of Organic Solar Cells Improved by Gold Nanoparticles in Buffer Layers.ACS APPLIED MATERIALS & INTERFACES,7(44),24430—24437.
MLA	Yang, YG,et al."Structure, Optical Absorption, and Performance of Organic Solar Cells Improved by Gold Nanoparticles in Buffer Layers".ACS APPLIED MATERIALS & INTERFACES 7.44(2015):24430—24437.

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