CAS OpenIR  > 中科院上海应用物理研究所2011-2018年
The Gibbs-free-energy landscape for the solute association in nanoconfined aqueous solutions
Zhao, L; Wang, CL; Fang, HP; Tu, YS; Tu, YS (reprint author), Yangzhou Univ, Coll Phys Sci & Technol, Yangzhou 225009, Peoples R China.
2015
Source PublicationNUCLEAR SCIENCE AND TECHNIQUES
ISSN1001-8042
Volume26Issue:3Pages:
Subtype期刊文献
AbstractThe theoretical model and the numerical analyses on the Gibbs-free-energy of the association states of amphiphilic molecules in nanoconfined aqueous solutions are presented in detail. We exhibit the continuous change of the Gibbs-free-energy trend, which plays a critical role in the association states of the system transforming from the dispersion state, through the "reversible state", and finally to the aggregation state in amphiphilic molecule solutions. Furthermore, for the "reversible state", we present the difference in the free-energy barrier heights of the dispersion state and aggregation state, resulting from the competition between the entropy, which makes the solute molecules evenly disperse in the solution and the energy contribution driving the amphiphilic molecules to aggregate into a larger cluster. These findings provide a comprehensive understanding of confinement effects on the solute association processes in aqueous solutions and may further improve the techniques of material fabrication.
KeywordSimulations Nucleation Dynamics Confinement Nanotubes Micelles Growth
Language英语
WOS IDWOS:000358109700017
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/25074
Collection中科院上海应用物理研究所2011-2018年
Corresponding AuthorTu, YS (reprint author), Yangzhou Univ, Coll Phys Sci & Technol, Yangzhou 225009, Peoples R China.
Recommended Citation
GB/T 7714
Zhao, L,Wang, CL,Fang, HP,et al. The Gibbs-free-energy landscape for the solute association in nanoconfined aqueous solutions[J]. NUCLEAR SCIENCE AND TECHNIQUES,2015,26(3):—.
APA Zhao, L,Wang, CL,Fang, HP,Tu, YS,&Tu, YS .(2015).The Gibbs-free-energy landscape for the solute association in nanoconfined aqueous solutions.NUCLEAR SCIENCE AND TECHNIQUES,26(3),—.
MLA Zhao, L,et al."The Gibbs-free-energy landscape for the solute association in nanoconfined aqueous solutions".NUCLEAR SCIENCE AND TECHNIQUES 26.3(2015):—.
Files in This Item: Download All
File Name/Size DocType Version Access License
The Gibbs-free-energ(476KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Download
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhao, L]'s Articles
[Wang, CL]'s Articles
[Fang, HP]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhao, L]'s Articles
[Wang, CL]'s Articles
[Fang, HP]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhao, L]'s Articles
[Wang, CL]'s Articles
[Fang, HP]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: The Gibbs-free-energy landscape for the solute association in nanoconfined aqueous solutions.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.