Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system
Wang, K; Fei, ZJ; Wang, J; Wu, Z; Li, CH; Xie, LD; Wang, K (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China.
2015
发表期刊MATERIALS CHEMISTRY AND PHYSICS
ISSN0254-0584
卷号163页码:73—87
文章类型期刊文献
摘要The present investigation is aimed at deriving a set of self-consistent thermodynamic functions for the AgCl-CoCl2-InCl3-KCl quaternary system within the framework of the CALPHAD approach. All the previous reported thermodynamic parameters for the binary subsystems were initially reviewed and adopted, and critical thermodynamic evaluations and optimizations were later performed on the unavailable AgCl-KCl and InCl3-KCl systems in terms of the required phase equilibria and thermochemical data from experimental measurements and theoretical predictions (First-principles method and empirical equation). The Modified Quasi-Chemical model were applied to describing the molten salt phase, while all the intermediate phases were treated as the stoichiometric compounds due to no observation of the homogeneity composition range. Various phase equilibria and thermodynamic properties in the ternary and quaternary systems could be facilely calculated based upon the ultimate thermodynamic database established in this case, which will support beneficial instructions in the related industrial processes. (C) 2015 Elsevier B.V. All rights reserved.
关键词Quasi-chemical Model Electromotive-force Measurements Silver-chloride Agcl-kcl Potassium-chloride Halide Mixtures Salt Systems Optimization Trichloride Pseudopotentials
语种英语
WOS记录号WOS:000365361500009
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/25081
专题中科院上海应用物理研究所2011-2018年
通讯作者Wang, K (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China.
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Wang, K,Fei, ZJ,Wang, J,et al. Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system[J]. MATERIALS CHEMISTRY AND PHYSICS,2015,163:73—87.
APA Wang, K.,Fei, ZJ.,Wang, J.,Wu, Z.,Li, CH.,...&Wang, K .(2015).Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system.MATERIALS CHEMISTRY AND PHYSICS,163,73—87.
MLA Wang, K,et al."Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system".MATERIALS CHEMISTRY AND PHYSICS 163(2015):73—87.
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