CAS OpenIR  > 中科院上海应用物理研究所2011-2018年
Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system
Wang, K; Fei, ZJ; Wang, J; Wu, Z; Li, CH; Xie, LD; Wang, K (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China.
2015
Source PublicationMATERIALS CHEMISTRY AND PHYSICS
ISSN0254-0584
Volume163Pages:73—87
Subtype期刊文献
AbstractThe present investigation is aimed at deriving a set of self-consistent thermodynamic functions for the AgCl-CoCl2-InCl3-KCl quaternary system within the framework of the CALPHAD approach. All the previous reported thermodynamic parameters for the binary subsystems were initially reviewed and adopted, and critical thermodynamic evaluations and optimizations were later performed on the unavailable AgCl-KCl and InCl3-KCl systems in terms of the required phase equilibria and thermochemical data from experimental measurements and theoretical predictions (First-principles method and empirical equation). The Modified Quasi-Chemical model were applied to describing the molten salt phase, while all the intermediate phases were treated as the stoichiometric compounds due to no observation of the homogeneity composition range. Various phase equilibria and thermodynamic properties in the ternary and quaternary systems could be facilely calculated based upon the ultimate thermodynamic database established in this case, which will support beneficial instructions in the related industrial processes. (C) 2015 Elsevier B.V. All rights reserved.
KeywordQuasi-chemical Model Electromotive-force Measurements Silver-chloride Agcl-kcl Potassium-chloride Halide Mixtures Salt Systems Optimization Trichloride Pseudopotentials
Language英语
WOS IDWOS:000365361500009
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/25081
Collection中科院上海应用物理研究所2011-2018年
Corresponding AuthorWang, K (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China.
Recommended Citation
GB/T 7714
Wang, K,Fei, ZJ,Wang, J,et al. Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system[J]. MATERIALS CHEMISTRY AND PHYSICS,2015,163:73—87.
APA Wang, K.,Fei, ZJ.,Wang, J.,Wu, Z.,Li, CH.,...&Wang, K .(2015).Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system.MATERIALS CHEMISTRY AND PHYSICS,163,73—87.
MLA Wang, K,et al."Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system".MATERIALS CHEMISTRY AND PHYSICS 163(2015):73—87.
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