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| Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system | |
| Wang, K; Fei, ZJ; Wang, J; Wu, Z; Li, CH; Xie, LD; Wang, K (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China. | |
| 2015 | |
| Source Publication | MATERIALS CHEMISTRY AND PHYSICS
 |
| ISSN | 0254-0584 |
| Volume | 163Pages:73—87 |
| Subtype | 期刊文献 |
| Abstract | The present investigation is aimed at deriving a set of self-consistent thermodynamic functions for the AgCl-CoCl2-InCl3-KCl quaternary system within the framework of the CALPHAD approach. All the previous reported thermodynamic parameters for the binary subsystems were initially reviewed and adopted, and critical thermodynamic evaluations and optimizations were later performed on the unavailable AgCl-KCl and InCl3-KCl systems in terms of the required phase equilibria and thermochemical data from experimental measurements and theoretical predictions (First-principles method and empirical equation). The Modified Quasi-Chemical model were applied to describing the molten salt phase, while all the intermediate phases were treated as the stoichiometric compounds due to no observation of the homogeneity composition range. Various phase equilibria and thermodynamic properties in the ternary and quaternary systems could be facilely calculated based upon the ultimate thermodynamic database established in this case, which will support beneficial instructions in the related industrial processes. (C) 2015 Elsevier B.V. All rights reserved. |
| Keyword | Quasi-chemical Model Electromotive-force Measurements Silver-chloride Agcl-kcl Potassium-chloride Halide Mixtures Salt Systems Optimization Trichloride Pseudopotentials |
| Language | 英语 |
| WOS ID | WOS:000365361500009 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/25081 |
| Collection | 中科院上海应用物理研究所2011-2018年 |
| Corresponding Author | Wang, K (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China. |
| Recommended Citation GB/T 7714 | Wang, K,Fei, ZJ,Wang, J,et al. Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system[J]. MATERIALS CHEMISTRY AND PHYSICS,2015,163:73—87. |
| APA | Wang, K.,Fei, ZJ.,Wang, J.,Wu, Z.,Li, CH.,...&Wang, K .(2015).Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system.MATERIALS CHEMISTRY AND PHYSICS,163,73—87. |
| MLA | Wang, K,et al."Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system".MATERIALS CHEMISTRY AND PHYSICS 163(2015):73—87. |
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| Thermodynamic descri（1116KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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