Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Covalent immobilization of metal-organic frameworks onto the surface of nylon-a new approach to the functionalization and coloration of textiles | |
| Yu, M; Li, WX; Wang, ZQ; Zhang, BW; Ma, HJ; Li, LF; Li, JY; Li, JY (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, CAS Ctr Innovat Adv Nucl Energy, Shanghai 201800, Peoples R China. | |
| 2016 | |
| 发表期刊 | SCIENTIFIC REPORTS
 |
| ISSN | 2045-2322 |
| 卷号 | 6期号:-页码:— |
| 文章类型 | 期刊文献 |
| 摘要 | The prevention of refractory organic pollution caused by conventional dyeing and the development of new fabrics with various functions are two issues to be solved urgently in the field of textile fabrication. Here, we report a new environmentally friendly route for the simultaneous coloration and functionalization of textiles by the covalent immobilization of a metal-organic framework, Cr-based MIL-101(Cr), onto the surfaces of nylon fabrics by co-graft polymerization with 2-hydroxyethyl acrylate initiated by gamma-ray irradiation. The Cr(III) clusters color the nylon fabric, and the color intensity varies with the MIL-101 content, providing a "green" textile coloration method that is different from conventional dyeing processes. An X-ray diffraction (XRD) analysis shows that the nanoporous structure of the original MIL-101 particles is retained during radiation-induced graft polymerization. Numerous nanopores are introduced onto the surface of the nylon fabric, which demonstrated better sustained-release-of-aroma performance versus pristine nylon fabric in tests. The modified fabrics exhibit laundering durability, with MIL-101 nanoparticles intact on the nylon surface after 30 h of dry cleaning. |
| 关键词 | Superhydrophobic Cotton Fabrics Laundering Durability Graft-polymerization Water Nanoparticles Mof Methacrylate Mil-101(Cr) Adsorption Separation |
| DOI | 10.1038/srep22796 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000371465400001 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.sinap.ac.cn/handle/331007/25672 |
| 专题 | 中科院上海应用物理研究所2011-2018年 |
| 通讯作者 | Li, JY (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, CAS Ctr Innovat Adv Nucl Energy, Shanghai 201800, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Yu, M,Li, WX,Wang, ZQ,et al. Covalent immobilization of metal-organic frameworks onto the surface of nylon-a new approach to the functionalization and coloration of textiles[J]. SCIENTIFIC REPORTS,2016,6(-):—. |
| APA | Yu, M.,Li, WX.,Wang, ZQ.,Zhang, BW.,Ma, HJ.,...&Li, JY .(2016).Covalent immobilization of metal-organic frameworks onto the surface of nylon-a new approach to the functionalization and coloration of textiles.SCIENTIFIC REPORTS,6(-),—. |
| MLA | Yu, M,et al."Covalent immobilization of metal-organic frameworks onto the surface of nylon-a new approach to the functionalization and coloration of textiles".SCIENTIFIC REPORTS 6.-(2016):—. |
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