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Covalent immobilization of metal-organic frameworks onto the surface of nylon-a new approach to the functionalization and coloration of textiles
Yu, M; Li, WX; Wang, ZQ; Zhang, BW; Ma, HJ; Li, LF; Li, JY; Li, JY (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, CAS Ctr Innovat Adv Nucl Energy, Shanghai 201800, Peoples R China.
2016
Source PublicationSCIENTIFIC REPORTS
ISSN2045-2322
Volume6Issue:-Pages:
Subtype期刊文献
AbstractThe prevention of refractory organic pollution caused by conventional dyeing and the development of new fabrics with various functions are two issues to be solved urgently in the field of textile fabrication. Here, we report a new environmentally friendly route for the simultaneous coloration and functionalization of textiles by the covalent immobilization of a metal-organic framework, Cr-based MIL-101(Cr), onto the surfaces of nylon fabrics by co-graft polymerization with 2-hydroxyethyl acrylate initiated by gamma-ray irradiation. The Cr(III) clusters color the nylon fabric, and the color intensity varies with the MIL-101 content, providing a "green" textile coloration method that is different from conventional dyeing processes. An X-ray diffraction (XRD) analysis shows that the nanoporous structure of the original MIL-101 particles is retained during radiation-induced graft polymerization. Numerous nanopores are introduced onto the surface of the nylon fabric, which demonstrated better sustained-release-of-aroma performance versus pristine nylon fabric in tests. The modified fabrics exhibit laundering durability, with MIL-101 nanoparticles intact on the nylon surface after 30 h of dry cleaning.
KeywordSuperhydrophobic Cotton Fabrics Laundering Durability Graft-polymerization Water Nanoparticles Mof Methacrylate Mil-101(Cr) Adsorption Separation
DOI10.1038/srep22796
Indexed BySCI
Language英语
WOS IDWOS:000371465400001
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/25672
Collection中科院上海应用物理研究所2011-2018年
Corresponding AuthorLi, JY (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, CAS Ctr Innovat Adv Nucl Energy, Shanghai 201800, Peoples R China.
Recommended Citation
GB/T 7714
Yu, M,Li, WX,Wang, ZQ,et al. Covalent immobilization of metal-organic frameworks onto the surface of nylon-a new approach to the functionalization and coloration of textiles[J]. SCIENTIFIC REPORTS,2016,6(-):—.
APA Yu, M.,Li, WX.,Wang, ZQ.,Zhang, BW.,Ma, HJ.,...&Li, JY .(2016).Covalent immobilization of metal-organic frameworks onto the surface of nylon-a new approach to the functionalization and coloration of textiles.SCIENTIFIC REPORTS,6(-),—.
MLA Yu, M,et al."Covalent immobilization of metal-organic frameworks onto the surface of nylon-a new approach to the functionalization and coloration of textiles".SCIENTIFIC REPORTS 6.-(2016):—.
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