Effect of strongly bound copper species in copper-ceria catalyst for preferential oxidation of carbon monoxide
Du, PP; Wang, WW; Jia, CJ; Song, QS; Huang, YY; Si, R; Si, R (reprint author), Chinese Acad Sci, Shanghai Synchrotron Radiat Facil, Shanghai Inst Appl Phys, Shanghai, Peoples R China.; Jia, CJ (reprint author), Shandong Univ, Key Lab Colloid & Interface Chem, Key Lab Special Aggregated Mat, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.
2016
发表期刊APPLIED CATALYSIS A-GENERAL
ISSN0926-860X
卷号518期号:-页码:87—101
文章类型期刊文献
摘要Copper-ceria catalysts with the Cu contents up to 40 at.% were prepared by the coprecipitation method. Ammonium carbonate was used as the leaching agent on the as-calcined samples to remove the weakly bound copper species. The parent and leached catalysts were tested for the preferential oxidation of carbon monoxide (CO-PROX) reaction from 40 to 200 degrees C in 1%CO/1%O-2/50%H-2/N-2 with a space velocity of 60,000 mL h(-1) g(cat)(-1). When the Cu doping amount reached 30 at.%, the stable and constant CO-PROX reactivity, including CO conversion and 02 selectivity, was presented for both parent and ammonium carbonate leached catalysts. The fresh and used samples have been carefully characterized by various techniques such as power X-ray diffraction (XRD), X-ray absorption fine structure (XAFS), transmission electron microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS) and temperature-programmed reduction by hydrogen (H-2-TPR). It was confirmed that there are two different types of copper species, i.e. weakly bound CuOx clusters and strongly bound Cu-[O-x]-Ce structure, in both parent and leached catalysts. Furthermore, we have demonstrated that the weakly bound CuOx clusters removed by ammonium carbonate can be recovered by the migration of Cu-[O-x]-Ce species under the reduction or reaction conditions. The strongly bound copper species in CeO2 have been identified to be the reservoir for the active Cu sites for CO-PROX. (C) 2015 Elsevier B.V. All rights reserved.
关键词X-ray-absorption Water-gas Shift Selective Co Oxidation Fuel-cell Applications Cuo-ceo2 Catalysts Oxide Catalyst In-situ Cuo/ceo2 Catalysts Redox Properties H-2-rich Gas
DOI10.1016/j.apcata.2015.10.041
收录类别SCI
语种英语
WOS记录号WOS:000377309600008
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/25700
专题中科院上海应用物理研究所2011-2018年
通讯作者Si, R (reprint author), Chinese Acad Sci, Shanghai Synchrotron Radiat Facil, Shanghai Inst Appl Phys, Shanghai, Peoples R China.; Jia, CJ (reprint author), Shandong Univ, Key Lab Colloid & Interface Chem, Key Lab Special Aggregated Mat, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.
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Du, PP,Wang, WW,Jia, CJ,et al. Effect of strongly bound copper species in copper-ceria catalyst for preferential oxidation of carbon monoxide[J]. APPLIED CATALYSIS A-GENERAL,2016,518(-):87—101.
APA Du, PP.,Wang, WW.,Jia, CJ.,Song, QS.,Huang, YY.,...&Jia, CJ .(2016).Effect of strongly bound copper species in copper-ceria catalyst for preferential oxidation of carbon monoxide.APPLIED CATALYSIS A-GENERAL,518(-),87—101.
MLA Du, PP,et al."Effect of strongly bound copper species in copper-ceria catalyst for preferential oxidation of carbon monoxide".APPLIED CATALYSIS A-GENERAL 518.-(2016):87—101.
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