Effects on the oriented structure and mechanical properties of carbon fibers by pre-irradiating polyacrylonitrile fibers with gamma ray
Zhao, WZ; Lu, YG; Zhou, LX; Jiang, JQ; Wang, J; Chen, Q; Tian, F; Lu, YG (reprint author), Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China.
2016
发表期刊JOURNAL OF MATERIALS SCIENCE
ISSN0022-2461
卷号51期号:15页码:7073—7084
文章类型期刊文献
摘要Carbon fibers (CFs) were prepared from polyacrylonitrile fibers pre-irradiated with gamma-ray irradiation in air prior to heat treatment and then by continuous stabilization and carbonization. The structural changes of fibers during heat treatment and the mechanical properties of the resultant CFs were investigated using dynamic mechanical analysis, wide-angle X-ray diffraction, small-angle X-ray scattering, and universal testing machine. It is found that not only the stabilization time was shortened with the increasing absorbed doses, but also the preferred orientation of carbon layers in the CFs was increased initially with the increasing absorbed doses and then decreased. Consequently, the tensile strength and Young's modulus of CFs were increased by 13.2 and 2.6 % at an appropriate dose, respectively, in which skin-core structure in CFs was relieved according to SEM images. Hence, it is believed that irradiation technology-assisted stabilization has a significant potential in CF industry.
关键词Oxidative Stabilization Precursor Fibers Radiation Scattering Evolution Deformation Orientation Strength Kinetics Behavior
DOI10.1007/s10853-016-9875-x
收录类别SCI
语种英语
WOS记录号WOS:000376468500003
引用统计
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/25705
专题中科院上海应用物理研究所2011-2018年
通讯作者Lu, YG (reprint author), Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China.
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GB/T 7714
Zhao, WZ,Lu, YG,Zhou, LX,et al. Effects on the oriented structure and mechanical properties of carbon fibers by pre-irradiating polyacrylonitrile fibers with gamma ray[J]. JOURNAL OF MATERIALS SCIENCE,2016,51(15):7073—7084.
APA Zhao, WZ.,Lu, YG.,Zhou, LX.,Jiang, JQ.,Wang, J.,...&Lu, YG .(2016).Effects on the oriented structure and mechanical properties of carbon fibers by pre-irradiating polyacrylonitrile fibers with gamma ray.JOURNAL OF MATERIALS SCIENCE,51(15),7073—7084.
MLA Zhao, WZ,et al."Effects on the oriented structure and mechanical properties of carbon fibers by pre-irradiating polyacrylonitrile fibers with gamma ray".JOURNAL OF MATERIALS SCIENCE 51.15(2016):7073—7084.
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