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Electrochemical determination of arsenic(III) with ultra-high anti-interference performance using Au-Cu bimetallic nanoparticles
Yang, M; Guo, Z; Li, LN; Huang, YY; Liu, JH; Zhou, Q; Chen, X; Huang, XJ; Huang, XJ (reprint author), Chinese Acad Sci, Inst Intelligent Machines, Hefei 230031, Peoples R China.
2016
Source PublicationSENSORS AND ACTUATORS B-CHEMICAL
ISSN0925-4005
Volume231Issue:-Pages:70—78
Subtype期刊文献
AbstractBimetallic nanoparticles provide a new opportunity for enhancing electrocatalytic activity because of some possible synergetic effects. In this study, different compositions of Au-Cu bimetallic nanoparticles are prepared via a simple hydrothermal method. The structure of Au-Cu bimetallic nanoparticles is characterized by using X-ray absorption fine structure (XAFS) techniques, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The correlations between electrochemical performance and the compositions of Au-Cu bimetallic nanoparticles on the determination of arsenic(III) are investigated through square wave anodic stripping voltammetry (SWASV). It is found that the amount of copper (Cu) in Au-Cu bimetallic nanoparticles is critical to the detection of arsenic(III). The XAFS results indicated that the Au-Au bond length (RAu-Au) can be influenced by the Cu concentration in the materials. Different RAu-Au of Au-Cu nanoparticles lead to the different electrochemical catalytic activity toward arsenic(III), further revealing the different electrochemical behavior. Compared with Au nanoparticles and commercial Au electrode, the Au-Cu bimetallic nanoparticles showed enhanced electrochemical performance with high sensitivity at ppb level, low detection limit. Moreover, the Au89Cu11 bimetallic nanoparticles exhibited ultra-high anti-interference performance on the detection of arsenic(III). (C) 2016 Elsevier B.V. All rights reserved.
KeywordGlassy-carbon Electrodes Cathodic Stripping Voltammetry Gold-copper Nanoparticles One-step Synthesis Alloy Nanoparticles Selective Detection Facile Synthesis Trace Amounts Formic-acid Oxidation
DOI10.1016/j.snb.2016.03.009
Indexed BySCI
Language英语
WOS IDWOS:000374330900009
Citation statistics
Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/25707
Collection中科院上海应用物理研究所2011-2018年
Corresponding AuthorChen, X; Huang, XJ (reprint author), Chinese Acad Sci, Inst Intelligent Machines, Hefei 230031, Peoples R China.
Recommended Citation
GB/T 7714
Yang, M,Guo, Z,Li, LN,et al. Electrochemical determination of arsenic(III) with ultra-high anti-interference performance using Au-Cu bimetallic nanoparticles[J]. SENSORS AND ACTUATORS B-CHEMICAL,2016,231(-):70—78.
APA Yang, M.,Guo, Z.,Li, LN.,Huang, YY.,Liu, JH.,...&Huang, XJ .(2016).Electrochemical determination of arsenic(III) with ultra-high anti-interference performance using Au-Cu bimetallic nanoparticles.SENSORS AND ACTUATORS B-CHEMICAL,231(-),70—78.
MLA Yang, M,et al."Electrochemical determination of arsenic(III) with ultra-high anti-interference performance using Au-Cu bimetallic nanoparticles".SENSORS AND ACTUATORS B-CHEMICAL 231.-(2016):70—78.
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