Enhanced Aerogen- Interaction by a Cation- Force
Miao, JJ; Song, B; Gao, Y; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 201800, Peoples R China.; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China.
2016
发表期刊CHEMISTRY-A EUROPEAN JOURNAL
ISSN0947-6539
卷号22期号:8页码:2586—2589
文章类型期刊文献
摘要The interaction between a noble gas atom and an aromatic -electron system, which mainly originates from the London dispersion force, is very weak and has not attracted enough attention yet. Herein, we reported a type of notably enhanced aerogen- interaction between cation-systems and noble gas atoms. The binding strength of a divalent cation-system with a xenon atom is comparable to a moderate hydrogen bond (up to ca.7 kcalmol(-1)), whereas krypton and argon atoms produce slightly weaker interactions. Energy-decomposition analysis reveals that the induction interaction is responsible for the stabilization of divalent cation-Xe species besides the dispersion interaction. Our results might be helpful to increase the understanding of some unsolved mysteries of aerogens.
关键词Pi Interactions Aromatic Rings Noncovalent Interactions Biological Recognition Compliance Constants Perturbation-theory Xenon Inhibition Complexes Strengths
DOI10.1002/chem.201504210
收录类别SCI
语种英语
WOS记录号WOS:000370193000004
引用统计
被引频次:12[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/25713
专题中科院上海应用物理研究所2011-2018年
通讯作者Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 201800, Peoples R China.; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China.
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Miao, JJ,Song, B,Gao, Y,et al. Enhanced Aerogen- Interaction by a Cation- Force[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(8):2586—2589.
APA Miao, JJ,Song, B,Gao, Y,Gao, Y ,&Gao, Y .(2016).Enhanced Aerogen- Interaction by a Cation- Force.CHEMISTRY-A EUROPEAN JOURNAL,22(8),2586—2589.
MLA Miao, JJ,et al."Enhanced Aerogen- Interaction by a Cation- Force".CHEMISTRY-A EUROPEAN JOURNAL 22.8(2016):2586—2589.
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