中国科学院上海应用物理研究所机构知识库
Advanced  
CAS OpenIR  > 中科院上海应用物理研究所2011-2017年  > 期刊论文
题名:
Enhanced Aerogen- Interaction by a Cation- Force
作者: Miao, JJ; Song, B; Gao, Y
刊名: CHEMISTRY-A EUROPEAN JOURNAL
出版日期: 2016
卷号: 22, 期号:8, 页码:2586—2589
关键词: PI INTERACTIONS ; AROMATIC RINGS ; NONCOVALENT INTERACTIONS ; BIOLOGICAL RECOGNITION ; COMPLIANCE CONSTANTS ; PERTURBATION-THEORY ; XENON ; INHIBITION ; COMPLEXES ; STRENGTHS
DOI: 10.1002/chem.201504210
通讯作者: Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 201800, Peoples R China. ; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China.
文章类型: 期刊文献
英文摘要: The interaction between a noble gas atom and an aromatic -electron system, which mainly originates from the London dispersion force, is very weak and has not attracted enough attention yet. Herein, we reported a type of notably enhanced aerogen- interaction between cation-systems and noble gas atoms. The binding strength of a divalent cation-system with a xenon atom is comparable to a moderate hydrogen bond (up to ca.7 kcalmol(-1)), whereas krypton and argon atoms produce slightly weaker interactions. Energy-decomposition analysis reveals that the induction interaction is responsible for the stabilization of divalent cation-Xe species besides the dispersion interaction. Our results might be helpful to increase the understanding of some unsolved mysteries of aerogens.
收录类别: SCI
语种: 英语
WOS记录号: WOS:000370193000004
ISSN号: 0947-6539
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sinap.ac.cn/handle/331007/25713
Appears in Collections:中科院上海应用物理研究所2011-2017年_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
Enhanced Aerogen- Interaction by a Cation- Force.pdf(870KB)期刊论文作者接受稿开放获取View Download

Recommended Citation:
Miao, JJ,Song, B,Gao, Y. Enhanced Aerogen- Interaction by a Cation- Force[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016-01-01,22(8):2586—2589.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Miao, JJ]'s Articles
[Song, B]'s Articles
[Gao, Y]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Miao, JJ]‘s Articles
[Song, B]‘s Articles
[Gao, Y]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: Enhanced Aerogen- Interaction by a Cation- Force.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace