CAS OpenIR  > 中科院上海应用物理研究所2011-2018年
Enhanced Aerogen- Interaction by a Cation- Force
Miao, JJ; Song, B; Gao, Y; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 201800, Peoples R China.; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China.
2016
Source PublicationCHEMISTRY-A EUROPEAN JOURNAL
ISSN0947-6539
Volume22Issue:8Pages:2586—2589
Subtype期刊文献
AbstractThe interaction between a noble gas atom and an aromatic -electron system, which mainly originates from the London dispersion force, is very weak and has not attracted enough attention yet. Herein, we reported a type of notably enhanced aerogen- interaction between cation-systems and noble gas atoms. The binding strength of a divalent cation-system with a xenon atom is comparable to a moderate hydrogen bond (up to ca.7 kcalmol(-1)), whereas krypton and argon atoms produce slightly weaker interactions. Energy-decomposition analysis reveals that the induction interaction is responsible for the stabilization of divalent cation-Xe species besides the dispersion interaction. Our results might be helpful to increase the understanding of some unsolved mysteries of aerogens.
KeywordPi Interactions Aromatic Rings Noncovalent Interactions Biological Recognition Compliance Constants Perturbation-theory Xenon Inhibition Complexes Strengths
DOI10.1002/chem.201504210
Indexed BySCI
Language英语
WOS IDWOS:000370193000004
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/25713
Collection中科院上海应用物理研究所2011-2018年
Corresponding AuthorGao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 201800, Peoples R China.; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China.
Recommended Citation
GB/T 7714
Miao, JJ,Song, B,Gao, Y,et al. Enhanced Aerogen- Interaction by a Cation- Force[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(8):2586—2589.
APA Miao, JJ,Song, B,Gao, Y,Gao, Y ,&Gao, Y .(2016).Enhanced Aerogen- Interaction by a Cation- Force.CHEMISTRY-A EUROPEAN JOURNAL,22(8),2586—2589.
MLA Miao, JJ,et al."Enhanced Aerogen- Interaction by a Cation- Force".CHEMISTRY-A EUROPEAN JOURNAL 22.8(2016):2586—2589.
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