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| Nanocrystalline iron-boron catalysts for low-temperature CO hydrogenation: Selective liquid fuel production and structure-activity correlation | |
| Xu, K; Cheng, Y; Lin, J; Wang, H; Xie, SH; Pei, Y; Yan, SR; Qiao, MH; Li, ZH; Zong, BN; Qiao, MH (reprint author), Fudan Univ, Dept Chem, Collaborat Innovat Ctr Chem Energy Mat, Shanghai 200433, Peoples R China.; Qiao, MH (reprint author), Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China.; Zong, BN (reprint author), SINOPEC, Res Inst Petr Proc, State Key Lab Catalyt Mat & Chem Engn, Beijing 100083, Peoples R China. | |
| 2016 | |
| 发表期刊 | JOURNAL OF CATALYSIS
 |
| ISSN | 0021-9517 |
| 卷号 | 339期号:-页码:102—110 |
| 文章类型 | 期刊文献 |
| 摘要 | Low-temperature Fischer-Tropsch synthesis (LTFTS) is one of the green routes for liquid fuel production. We prepared nanocrystalline Fe-B catalysts with different particle sizes and microstructures by adjusting the addition sequence of the precursors. In situ carburization of the Fe-B catalysts at 423 K revealed that the addition sequence influenced the rate and degree of carburization pronouncedly. In LTFTS at 423 K, the Fe-B catalysts displayed similar, markedly high selectivity to liquid fuels, with similar to 48% for C-5-C-11 (gasoline fraction) and similar to 31% for C-12-C-20 (diesel fraction) hydrocarbons, and low selectivities to CO2 and CH4, manifesting excellent carbon atom economy over the non-noble Fe-B catalysts. While the carburization degree did not affect the product distribution, the activities of the Fe-B catalysts evolved positively with the epsilon-Fe2C content. Moreover, a good linear relationship was established between the Fe-Fe coordination number and the epsilon-Fe2C content. (C) 2016 Elsevier Inc. All rights reserved. |
| 关键词 | Fischer-tropsch Synthesis Fe Adsorption Dissociation Activation Surfaces Coverage Phase Alloy Dft |
| DOI | 10.1016/j.jcat.2016.03.035 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000378453700013 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.sinap.ac.cn/handle/331007/25780 |
| 专题 | 中科院上海应用物理研究所2011-2018年 |
| 通讯作者 | Qiao, MH (reprint author), Fudan Univ, Dept Chem, Collaborat Innovat Ctr Chem Energy Mat, Shanghai 200433, Peoples R China.; Qiao, MH (reprint author), Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China.; Zong, BN (reprint author), SINOPEC, Res Inst Petr Proc, State Key Lab Catalyt Mat & Chem Engn, Beijing 100083, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Xu, K,Cheng, Y,Lin, J,et al. Nanocrystalline iron-boron catalysts for low-temperature CO hydrogenation: Selective liquid fuel production and structure-activity correlation[J]. JOURNAL OF CATALYSIS,2016,339(-):102—110. |
| APA | Xu, K.,Cheng, Y.,Lin, J.,Wang, H.,Xie, SH.,...&Zong, BN .(2016).Nanocrystalline iron-boron catalysts for low-temperature CO hydrogenation: Selective liquid fuel production and structure-activity correlation.JOURNAL OF CATALYSIS,339(-),102—110. |
| MLA | Xu, K,et al."Nanocrystalline iron-boron catalysts for low-temperature CO hydrogenation: Selective liquid fuel production and structure-activity correlation".JOURNAL OF CATALYSIS 339.-(2016):102—110. |
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