Radiation induced graft polymerization of multi-walled carbon nanotubes for superhydrophobic composite membrane preparation
Zhang, BW; Xie, SY; Wei, RM; Ma, HJ; Yu, M; Li, LF; Li, JY; Li, JY (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, CAS Ctr Excellence TMSR Energy Syst, Shanghai 201800, Peoples R China.
2016
发表期刊SCIENCE CHINA-CHEMISTRY
ISSN1674-7291
卷号59期号:3页码:303—309
文章类型期刊文献
摘要Highly soluble multi-walled carbon nanotubes (MWNTs) were prepared by radiation-induced free radical graft polymerization of vinyl acetate (VAc) onto pristine MWNT surfaces. High resolution transmission electron microscopy (HR-TEM), Fourier transform infrared (FTIR) spectroscopy, and micro-Raman spectroscopy were used to confirm that poly(vinyl acetate) (PVAc) had been successfully grafted onto the surface of the MWNTs. The effects of experimental parameters on the degree of grafting (DG) of PVAc were also investigated, including adsorbed dose, dose rate, initial monomer concentration, and solvents. The grafted MWNTs (MWNTs-g-PVAc) exhibited good solubility in common organic solvents at high mass fraction. In addition, a superhydrophobic composite membrane could be readily fabricated by vacuum filtration of MWNTs-g-PVAc onto a supporting membrane, as was confirmed by water contact angle testing and visualization by scanning electron microscopy.
关键词Water Desalination Maleic-acid Films Functionalization Nanomaterials Dispersion Surfaces Acetate
DOI10.1007/s11426-015-5472-0
收录类别SCI
语种英语
WOS记录号WOS:000371314400008
引用统计
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/25820
专题中科院上海应用物理研究所2011-2018年
通讯作者Li, JY (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, CAS Ctr Excellence TMSR Energy Syst, Shanghai 201800, Peoples R China.
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Zhang, BW,Xie, SY,Wei, RM,et al. Radiation induced graft polymerization of multi-walled carbon nanotubes for superhydrophobic composite membrane preparation[J]. SCIENCE CHINA-CHEMISTRY,2016,59(3):303—309.
APA Zhang, BW.,Xie, SY.,Wei, RM.,Ma, HJ.,Yu, M.,...&Li, JY .(2016).Radiation induced graft polymerization of multi-walled carbon nanotubes for superhydrophobic composite membrane preparation.SCIENCE CHINA-CHEMISTRY,59(3),303—309.
MLA Zhang, BW,et al."Radiation induced graft polymerization of multi-walled carbon nanotubes for superhydrophobic composite membrane preparation".SCIENCE CHINA-CHEMISTRY 59.3(2016):303—309.
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