Single atom dispersed Rh-biphephos&PPh3@porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene
Li, CY; Yan, L; Lu, LL; Xiong, K; Wang, WL; Jiang, M; Liu, J; Song, XG; Zhan, ZP; Jiang, Z; Ding, YJ; Ding, YJ (reprint author), Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China.; Ding, YJ (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China.
2016
发表期刊GREEN CHEMISTRY
ISSN1463-9262
卷号18期号:10页码:2995—3005
文章类型期刊文献
摘要A vinyl functionalized biphephos ligand with high steric hindrance was copolymerized with tris(4-vinphenyl)phosphane and other ligands to afford efficient porous organic copolymers (POPs) through the solvothermal synthesis technique. By employing the copolymer self-supported heterogeneous Rh/CPOL-bp&P catalysts, the hydroformylation of propene to linear-butaldehyde can be performed efficiently in a continuous fixed-bed reactor with high regioselectivity (l/b > 24), activity (TOF > 1200 h(-1)) and stability (over 1000 h) under mild conditions (70 degrees C, 0.5 MPa), which represents a substantial improvement in the efficiency of this important industrial process. EXAFS and HAADF-STEM showed that the Rh was a single atom dispersion, which explained well the high efficiency of the Rh/CPOL-bp&P catalysts. Compared with liquid-liquid biphasic (LLB) and ionic liquid (IL) systems, this highly efficient solvent free system has the advantages of simple operability, and almost no waste emission, which meets the demands of green industrial processing.
关键词Supercritical Carbon-dioxide Gas-phase Hydroformylation Rhodium-biphephos-catalyst Modified Rh/sio2 Catalysts In-situ Formation Ionic-liquid Heterogeneous Catalysts Selective Hydroformylation Asymmetric Hydroformylation Propylene Carbonate
DOI10.1039/c6gc00728g
收录类别SCI
语种英语
WOS记录号WOS:000376082400012
引用统计
被引频次:23[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/25832
专题中科院上海应用物理研究所2011-2018年
通讯作者Yan, L; Ding, YJ (reprint author), Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China.; Ding, YJ (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China.
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GB/T 7714
Li, CY,Yan, L,Lu, LL,et al. Single atom dispersed Rh-biphephos&PPh3@porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene[J]. GREEN CHEMISTRY,2016,18(10):2995—3005.
APA Li, CY.,Yan, L.,Lu, LL.,Xiong, K.,Wang, WL.,...&Ding, YJ .(2016).Single atom dispersed Rh-biphephos&PPh3@porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene.GREEN CHEMISTRY,18(10),2995—3005.
MLA Li, CY,et al."Single atom dispersed Rh-biphephos&PPh3@porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene".GREEN CHEMISTRY 18.10(2016):2995—3005.
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