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| Structural Phase Transitions and Metallized Phenomena in Arsenic Telluride under High Pressure | |
| Zhao, JG; Yang, LX; Yu, ZH; Wang, Y; Li, CY; Yang, K; Liu, ZG; Wang, Y; Wang, Y (reprint author), Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, Nat Sci Res Ctr, Harbin 150080, Peoples R China.; Liu, ZG (reprint author), Harbin Inst Technol, Dept Phys, Harbin 150080, Peoples R China. | |
| 2016 | |
| Source Publication | INORGANIC CHEMISTRY
 |
| ISSN | 0020-1669 |
| Volume | 55Issue:8Pages:3907—3914 |
| Subtype | 期刊文献 |
| Abstract | In this study, first-principle,calculations, in situ angle-dispersive X-ray diffraction, and in situ electrical resistance measurements were performed on arsenic telluride (As2Te3) under high pressure. Structural phase transitions and metallized phenomena were observed from the calculated and experimental results. Upon compression, alpha-As2Te3 transforms into phases alpha' and alpha '' at similar to 5.09 and similar to 13.2 GPa, respectively, with two isostructural phase transitions. From 13.2 GPa, As2Te3 starts to transform into phase gamma, with one first-order monoclinic to monoclinic crystal structural phase transition. According to the first-principle calculations and electrical resistance measurements, the structural phase transitions in the compression process induce the transformation from an insulator (phase alpha) across a semimetal (phase alpha') into a metal (phases alpha '' and gamma). The evolution of the structure and transport property upon compression on As2Te3 is helpful for understanding the properties of other A(2)B(3)-type compounds under high, pressure. |
| Keyword | Topological Insulator Crystal Structure Sb2te3 Bi2te3 As2te3 Refinement Bcc Superconductivity Polymorphism Beta-as2te3 |
| DOI | 10.1021/acs.inorgchem.6b00073 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000374508600024 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/25845 |
| Collection | 中科院上海应用物理研究所2011-2018年 |
| Corresponding Author | Zhao, JG; Wang, Y (reprint author), Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, Nat Sci Res Ctr, Harbin 150080, Peoples R China.; Liu, ZG (reprint author), Harbin Inst Technol, Dept Phys, Harbin 150080, Peoples R China. |
| Recommended Citation GB/T 7714 | Zhao, JG,Yang, LX,Yu, ZH,et al. Structural Phase Transitions and Metallized Phenomena in Arsenic Telluride under High Pressure[J]. INORGANIC CHEMISTRY,2016,55(8):3907—3914. |
| APA | Zhao, JG.,Yang, LX.,Yu, ZH.,Wang, Y.,Li, CY.,...&Liu, ZG .(2016).Structural Phase Transitions and Metallized Phenomena in Arsenic Telluride under High Pressure.INORGANIC CHEMISTRY,55(8),3907—3914. |
| MLA | Zhao, JG,et al."Structural Phase Transitions and Metallized Phenomena in Arsenic Telluride under High Pressure".INORGANIC CHEMISTRY 55.8(2016):3907—3914. |
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| Structural Phase Tra（2996KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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