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A grand unified model for liganded gold clusters
Xu, WW; Zhu, BE; Zeng, XC; Gao, Y; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 201800, Peoples R China.; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China.; Zeng, XC (reprint author), Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA.; Zeng, XC (reprint author), Univ Sci & Technol China, Collaborat Innovat Ctr Chem Energy Mat, Hefei 230026, Anhui, Peoples R China.; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Sci Res Ctr, Shanghai 201204, Peoples R China.
2016
Source PublicationNature Communications
ISSN2041-1723
Volume7Pages:-
Subtype期刊论文
AbstractA grand unified model (GUM) is developed to achieve fundamental understanding of rich structures of all 71 liganded gold clusters reported to date. Inspired by the quark model by which composite particles (for example, protons and neutrons) are formed by combining three quarks (or flavours), here gold atoms are assigned three 'flavours' (namely, bottom, middle and top) to represent three possible valence states. The 'composite particles' in GUM are categorized into two groups: variants of triangular elementary block Au-3(2e) and tetrahedral elementary block Au-4(2e), all satisfying the duet rule (2e) of the valence shell, akin to the octet rule in general chemistry. The elementary blocks, when packed together, form the cores of liganded gold clusters. With the GUM, structures of 71 liganded gold clusters and their growth mechanism can be deciphered altogether. Although GUM is a predictive heuristic and may not be necessarily reflective of the actual electronic structure, several highly stable liganded gold clusters are predicted, thereby offering GUM-guided synthesis of liganded gold clusters by design.
DOI10.1038/ncomms13574
Indexed BySCI
Language英语
WOS IDWOS:000389302400001
Citation statistics
Cited Times:50[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/26405
Collection中科院上海应用物理研究所2011-2018年
Corresponding AuthorGao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 201800, Peoples R China.; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China.; Zeng, XC (reprint author), Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA.; Zeng, XC (reprint author), Univ Sci & Technol China, Collaborat Innovat Ctr Chem Energy Mat, Hefei 230026, Anhui, Peoples R China.; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Sci Res Ctr, Shanghai 201204, Peoples R China.
Recommended Citation
GB/T 7714
Xu, WW,Zhu, BE,Zeng, XC,et al. A grand unified model for liganded gold clusters[J]. Nature Communications,2016,7:-.
APA Xu, WW.,Zhu, BE.,Zeng, XC.,Gao, Y.,Gao, Y .,...&Gao, Y .(2016).A grand unified model for liganded gold clusters.Nature Communications,7,-.
MLA Xu, WW,et al."A grand unified model for liganded gold clusters".Nature Communications 7(2016):-.
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