A grand unified model for liganded gold clusters
Xu, WW; Zhu, BE; Zeng, XC; Gao, Y; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 201800, Peoples R China.; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China.; Zeng, XC (reprint author), Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA.; Zeng, XC (reprint author), Univ Sci & Technol China, Collaborat Innovat Ctr Chem Energy Mat, Hefei 230026, Anhui, Peoples R China.; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Sci Res Ctr, Shanghai 201204, Peoples R China.
2016
发表期刊Nature Communications
ISSN2041-1723
卷号7页码:-
文章类型期刊论文
摘要A grand unified model (GUM) is developed to achieve fundamental understanding of rich structures of all 71 liganded gold clusters reported to date. Inspired by the quark model by which composite particles (for example, protons and neutrons) are formed by combining three quarks (or flavours), here gold atoms are assigned three 'flavours' (namely, bottom, middle and top) to represent three possible valence states. The 'composite particles' in GUM are categorized into two groups: variants of triangular elementary block Au-3(2e) and tetrahedral elementary block Au-4(2e), all satisfying the duet rule (2e) of the valence shell, akin to the octet rule in general chemistry. The elementary blocks, when packed together, form the cores of liganded gold clusters. With the GUM, structures of 71 liganded gold clusters and their growth mechanism can be deciphered altogether. Although GUM is a predictive heuristic and may not be necessarily reflective of the actual electronic structure, several highly stable liganded gold clusters are predicted, thereby offering GUM-guided synthesis of liganded gold clusters by design.
DOI10.1038/ncomms13574
收录类别SCI
语种英语
WOS记录号WOS:000389302400001
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被引频次:38[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/26405
专题中科院上海应用物理研究所2011-2018年
通讯作者Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 201800, Peoples R China.; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China.; Zeng, XC (reprint author), Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA.; Zeng, XC (reprint author), Univ Sci & Technol China, Collaborat Innovat Ctr Chem Energy Mat, Hefei 230026, Anhui, Peoples R China.; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Sci Res Ctr, Shanghai 201204, Peoples R China.
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Xu, WW,Zhu, BE,Zeng, XC,et al. A grand unified model for liganded gold clusters[J]. Nature Communications,2016,7:-.
APA Xu, WW.,Zhu, BE.,Zeng, XC.,Gao, Y.,Gao, Y .,...&Gao, Y .(2016).A grand unified model for liganded gold clusters.Nature Communications,7,-.
MLA Xu, WW,et al."A grand unified model for liganded gold clusters".Nature Communications 7(2016):-.
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