A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI
Chen, LH; Zheng, T; Bao, SS; Zhang, LJ; Liu, HK; Zheng, LM; Wang, JQ; Wang, YX; Juan, DW; Chai, ZF; Albrecht-Schmitt, TE; Wang, SA; Wang, SA (reprint author), Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, 199 Renai Rd, Suzhou 215123, Peoples R China.; Wang, SA (reprint author), Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, 199 Renai Rd, Suzhou 215123, Peoples R China.
2016
发表期刊CHEMISTRY-A EUROPEAN JOURNAL
ISSN0947-6539
卷号22期号:34页码:11954-11957
文章类型期刊论文
摘要It is shown that (UO2+)-O-V ions can reside at (UO22+)-O-VI lattice sites during mild reduction and crystallization process under solvothermal conditions, yielding a complicated and rare mixed-valent uranium phosphonate compound that simultaneously contains U-IV, U-V, and U-VI. The presence of uranium with three oxidation states was confirmed by various characterization techniques, including X-ray crystallography, X-ray photoelectron, electron paramagnetic resonance, FTIR, UV/Vis-NIR absorption, and synchrotron radiation X-ray absorption spectroscopy, and magnetism measurements.
关键词Magnetism Mixed-valent Compounds Pentavalent Uranyl Solid-state Structure Uranium Phosphonate
DOI10.1002/chem.201602863
收录类别SCI
语种英语
WOS记录号WOS:000382925000007
引用统计
被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/26408
专题中科院上海应用物理研究所2011-2018年
通讯作者Juan, DW; Wang, SA (reprint author), Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, 199 Renai Rd, Suzhou 215123, Peoples R China.; Wang, SA (reprint author), Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, 199 Renai Rd, Suzhou 215123, Peoples R China.
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GB/T 7714
Chen, LH,Zheng, T,Bao, SS,et al. A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(34):11954-11957.
APA Chen, LH.,Zheng, T.,Bao, SS.,Zhang, LJ.,Liu, HK.,...&Wang, SA .(2016).A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI.CHEMISTRY-A EUROPEAN JOURNAL,22(34),11954-11957.
MLA Chen, LH,et al."A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI".CHEMISTRY-A EUROPEAN JOURNAL 22.34(2016):11954-11957.
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