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A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI | |
Chen, LH; Zheng, T; Bao, SS; Zhang, LJ; Liu, HK; Zheng, LM; Wang, JQ; Wang, YX; Juan, DW; Chai, ZF; Albrecht-Schmitt, TE; Wang, SA; Wang, SA (reprint author), Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, 199 Renai Rd, Suzhou 215123, Peoples R China.; Wang, SA (reprint author), Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, 199 Renai Rd, Suzhou 215123, Peoples R China. | |
2016 | |
Source Publication | CHEMISTRY-A EUROPEAN JOURNAL
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ISSN | 0947-6539 |
Volume | 22Issue:34Pages:11954-11957 |
Subtype | 期刊论文 |
Abstract | It is shown that (UO2+)-O-V ions can reside at (UO22+)-O-VI lattice sites during mild reduction and crystallization process under solvothermal conditions, yielding a complicated and rare mixed-valent uranium phosphonate compound that simultaneously contains U-IV, U-V, and U-VI. The presence of uranium with three oxidation states was confirmed by various characterization techniques, including X-ray crystallography, X-ray photoelectron, electron paramagnetic resonance, FTIR, UV/Vis-NIR absorption, and synchrotron radiation X-ray absorption spectroscopy, and magnetism measurements. |
Keyword | Magnetism Mixed-valent Compounds Pentavalent Uranyl Solid-state Structure Uranium Phosphonate |
DOI | 10.1002/chem.201602863 |
Indexed By | SCI |
Language | 英语 |
WOS ID | WOS:000382925000007 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/26408 |
Collection | 中科院上海应用物理研究所2011-2020年 |
Corresponding Author | Juan, DW; Wang, SA (reprint author), Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, 199 Renai Rd, Suzhou 215123, Peoples R China.; Wang, SA (reprint author), Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, 199 Renai Rd, Suzhou 215123, Peoples R China. |
Recommended Citation GB/T 7714 | Chen, LH,Zheng, T,Bao, SS,et al. A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(34):11954-11957. |
APA | Chen, LH.,Zheng, T.,Bao, SS.,Zhang, LJ.,Liu, HK.,...&Wang, SA .(2016).A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI.CHEMISTRY-A EUROPEAN JOURNAL,22(34),11954-11957. |
MLA | Chen, LH,et al."A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI".CHEMISTRY-A EUROPEAN JOURNAL 22.34(2016):11954-11957. |
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