A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI

doi:10.1002/chem.201602863

CAS OpenIR > 中科院上海应用物理研究所2011-2020年

	A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI
	Chen, LH; Zheng, T; Bao, SS; Zhang, LJ; Liu, HK; Zheng, LM; Wang, JQ; Wang, YX; Juan, DW; Chai, ZF; Albrecht-Schmitt, TE; Wang, SA; Wang, SA (reprint author), Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, 199 Renai Rd, Suzhou 215123, Peoples R China.; Wang, SA (reprint author), Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, 199 Renai Rd, Suzhou 215123, Peoples R China.
	2016
Source Publication	CHEMISTRY-A EUROPEAN JOURNAL
ISSN	0947-6539
Volume	22 Issue:34 Pages:11954-11957
Subtype	期刊论文
Abstract	It is shown that (UO2+)-O-V ions can reside at (UO22+)-O-VI lattice sites during mild reduction and crystallization process under solvothermal conditions, yielding a complicated and rare mixed-valent uranium phosphonate compound that simultaneously contains U-IV, U-V, and U-VI. The presence of uranium with three oxidation states was confirmed by various characterization techniques, including X-ray crystallography, X-ray photoelectron, electron paramagnetic resonance, FTIR, UV/Vis-NIR absorption, and synchrotron radiation X-ray absorption spectroscopy, and magnetism measurements.
Keyword	Magnetism Mixed-valent Compounds Pentavalent Uranyl Solid-state Structure Uranium Phosphonate
DOI	10.1002/chem.201602863
Indexed By	SCI
Language	英语
WOS ID	WOS:000382925000007
Citation statistics	Cited Times:26[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.sinap.ac.cn/handle/331007/26408
Collection	中科院上海应用物理研究所2011-2020年
Corresponding Author	Juan, DW; Wang, SA (reprint author), Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, 199 Renai Rd, Suzhou 215123, Peoples R China.; Wang, SA (reprint author), Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, 199 Renai Rd, Suzhou 215123, Peoples R China.
Recommended Citation GB/T 7714	Chen, LH,Zheng, T,Bao, SS,et al. A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(34):11954-11957.
APA	Chen, LH.,Zheng, T.,Bao, SS.,Zhang, LJ.,Liu, HK.,...&Wang, SA .(2016).A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI.CHEMISTRY-A EUROPEAN JOURNAL,22(34),11954-11957.
MLA	Chen, LH,et al."A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI".CHEMISTRY-A EUROPEAN JOURNAL 22.34(2016):11954-11957.

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