A new association state of solutes in nanoconfined aqueous solutions
Tu, YS; Zhao, L; Fang, HP; Fang, HP (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 201800, Peoples R China.; Fang, HP (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China.
2016
发表期刊SCIENCE CHINA-PHYSICS MECHANICS & ASTRONOMY
ISSN1674-7348
卷号59期号:11页码:-
文章类型期刊论文
摘要Recently, we have found a reversible transition between the dispersion and aggregation states of solute molecules in aqueous solutions confined in nanoscale geometry, where solutes exhibit distinct behavior in a new association state from that in the dispersion and aggregation states observed usually in macroscopic systems. However, it remains unknown whether this new association state of solute molecules found in nanoconfined systems would vanish with the system size increasing and approaching the macroscopic scale. Here, we achieve the phase diagram of solute association states by making the analyses of Gibbs free energy of solutes in nanoconfined aqueous solutions in detail. In the phase diagram, we observe a closed regime with a finite system size of nanoconfined aqueous solutions and a solute concentration range, only in which there exists the new association state of solutes with the reversible transition between the aggregation and dispersion states, and there indeed exists an upper limit of the system size for the new association state, around several tens nanometers. These findings regarding the intimate connection between the system size and the solute association behavior provides the comprehensive understanding of the association dynamics of solutes in nanoconfined environment.
关键词Solute Association States Reversible Transition Nanoconfined Aqueous Solutions Free Energy Barrier
DOI10.1007/s11433-016-0271-x
收录类别SCI
语种英语
WOS记录号WOS:000384561100003
引用统计
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/26409
专题中科院上海应用物理研究所2011-2018年
通讯作者Fang, HP (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 201800, Peoples R China.; Fang, HP (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China.
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Tu, YS,Zhao, L,Fang, HP,et al. A new association state of solutes in nanoconfined aqueous solutions[J]. SCIENCE CHINA-PHYSICS MECHANICS & ASTRONOMY,2016,59(11):-.
APA Tu, YS,Zhao, L,Fang, HP,Fang, HP ,&Fang, HP .(2016).A new association state of solutes in nanoconfined aqueous solutions.SCIENCE CHINA-PHYSICS MECHANICS & ASTRONOMY,59(11),-.
MLA Tu, YS,et al."A new association state of solutes in nanoconfined aqueous solutions".SCIENCE CHINA-PHYSICS MECHANICS & ASTRONOMY 59.11(2016):-.
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