A new layered nano hybrid perovskite film with enhanced resistance to moisturee-induced degradation
Jiang, WL; Ying, JF; Zhou, W; Shen, KC; Liu, X; Gao, XY; Guo, FQ; Gao, YM; Yang, TY; Gao, YM (reprint author), Jiangsu Univ Sci & Technol, Zhenjiang 212003, Peoples R China.
2016
发表期刊CHEMICAL PHYSICS LETTERS
ISSN0009-2614
卷号658页码:71-75
文章类型期刊论文
摘要In this paper, a new layered hybrid perovskite film ((EDA)(MA)(2)[Pb3I10]) was synthesized through one-step method. Ethylenediamine (EDA) cation was introduced into the perovskite lattice to synthesize a layered structure with improved resistance to degradation by humidity. The effects of humidity and time on crystal structure, composition, morphology and absorption spectra of (EDA)(MA)(2)[Pb3I10] were analyzed by in situ grazing incidence X-ray diffraction (GIXRD), scanning electron microscope (SEM), and UV-Vis spectroscope. The results reveal that a (EDA)(MA)(2)[Pb3I10] film is more moisture resistant than a CH3NH3PbI3 film which is widely used in the perovskite solar cell now. UV-Vis spectroscopy result also shows that the layered structure film is a suitable solar absorber with a bandgap (1.67 eV), which is close to the optimum value for solar photoelectric conversion. Compared to CH3NH3PbI3, the low-cost perovslcite structure offers greater tunability on a molecular level for further material optimization and possibility for widely used in the future. (C) 2016 Elsevier B.V. All rights reserved.
DOI10.1016/j.cplett.2016.05.054
收录类别SCI
语种英语
WOS记录号WOS:000382409800011
引用统计
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/26410
专题中科院上海应用物理研究所2011-2018年
通讯作者Gao, YM (reprint author), Jiangsu Univ Sci & Technol, Zhenjiang 212003, Peoples R China.
推荐引用方式
GB/T 7714
Jiang, WL,Ying, JF,Zhou, W,et al. A new layered nano hybrid perovskite film with enhanced resistance to moisturee-induced degradation[J]. CHEMICAL PHYSICS LETTERS,2016,658:71-75.
APA Jiang, WL.,Ying, JF.,Zhou, W.,Shen, KC.,Liu, X.,...&Gao, YM .(2016).A new layered nano hybrid perovskite film with enhanced resistance to moisturee-induced degradation.CHEMICAL PHYSICS LETTERS,658,71-75.
MLA Jiang, WL,et al."A new layered nano hybrid perovskite film with enhanced resistance to moisturee-induced degradation".CHEMICAL PHYSICS LETTERS 658(2016):71-75.
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