Bioleaching of chalcopyrite by Acidianus manzaensis under different constant pH

doi:10.1016/j.mineng.2016.07.019

CAS OpenIR > 中科院上海应用物理研究所2011-2018年

	Bioleaching of chalcopyrite by Acidianus manzaensis under different constant pH
	Liu, HC; Xia, JL; Nie, ZY; Ma, CY; Zheng, L; Hong, CH; Zhao, YD; Wen, W; Xia, JL (reprint author), Cent S Univ, Sch Minerals Proc & Bioengn, Changsha 410083, Peoples R China.
	2016
发表期刊	MINERALS ENGINEERING
ISSN	0892-6875
卷号	98 页码:80-89
文章类型	期刊论文
摘要	The bioleaching of pure chalcopyrite by thermophilic Archaea strain Acidianus manzaensis YN-25 under different constant pH was first comparatively investigated. Then the relevant sulfur speciation was analyzed by synchrotron radiation based X-ray diffraction (SR-XRD) and S K-edge X-ray absorption near edge structure ()CANES) spectroscopy. The acidity of the leaching solution was monitored at 3-h intervals to make it steady at pH 1.25, 1.50, 1.75, 2.00, 2.25 and 2.50, respectively. Leaching results showed that the copper ion extraction increased during chemical leaching but decreased during bioleaching when pH value decreased from 2.50 to 1.25. SR-XRD analysis showed that, during bioleaching, new elemental sulfur (5) phase was detected at all tested pH cases; new jarosite phase was detected at cases of pH 1.50 to 2.50; and jarosite gradually became a major phase when pH value increased. XANES analysis further showed that covellite was detected during bioleaching at cases of pH 1.25 to 2.00 at higher redox potential (ORP) value, while chalcocite and bornite were detected at cases of pH 2.25 and 2.50 at lower ORP value. These results suggested that the formation of S was mainly accounting for hindering the dissolution of chalcopyrite while the formation of bornite could accelerate the dissolution of chalcopyrite by A. manzaensis. (C) 2016 Elsevier Ltd. All rights reserved.
关键词	Bioleaching Chalcopyrite Acidianus Manzaensis Constant Ph Synchrotron Radiation Xanes
DOI	10.1016/j.mineng.2016.07.019
收录类别	SCI
语种	英语
WOS记录号	WOS:000385603200011
引用统计
文献类型	期刊论文
条目标识符	http://ir.sinap.ac.cn/handle/331007/26441
专题	中科院上海应用物理研究所2011-2018年
通讯作者	Xia, JL (reprint author), Cent S Univ, Sch Minerals Proc & Bioengn, Changsha 410083, Peoples R China.
推荐引用方式 GB/T 7714	Liu, HC,Xia, JL,Nie, ZY,et al. Bioleaching of chalcopyrite by Acidianus manzaensis under different constant pH[J]. MINERALS ENGINEERING,2016,98:80-89.
APA	Liu, HC.,Xia, JL.,Nie, ZY.,Ma, CY.,Zheng, L.,...&Xia, JL .(2016).Bioleaching of chalcopyrite by Acidianus manzaensis under different constant pH.MINERALS ENGINEERING,98,80-89.
MLA	Liu, HC,et al."Bioleaching of chalcopyrite by Acidianus manzaensis under different constant pH".MINERALS ENGINEERING 98(2016):80-89.

条目包含的文件		下载所有文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
Bioleaching of chalc（777KB）	期刊论文	作者接受稿	开放获取	CC BY-NC-SA	浏览下载