CAS OpenIR  > 中科院上海应用物理研究所2011-2018年
Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2
Zhang, CF; Wang, X; Li, MR; Zhang, ZX; Wang, YH; Si, R; Wang, F; Wang, F (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China.
2016
Source PublicationCHINESE JOURNAL OF CATALYSIS
ISSN0253-9837
Volume37Issue:9Pages:1569-1578
Subtype期刊论文
AbstractWe present an efficient approach for the chemoselective synthesis of arylamines from nitroarenes and formate over an oxygen-implanted MoS2 catalyst (O-MoS2). O-MoS2 was prepared by incomplete sulfidation and reduction of an ammonium molybdate precursor. A number of Mo-O bonds were implanted in the as-synthesized ultrathin O-MoS2 nanosheets. As a consequence of the different coordination geometries of O (MoS2) and S (MoS2), and lengths of the Mo-O and Mo-S bonds, the implanted Mo-O bonds induced obvious defects and more coordinatively unsaturated (CUS) Mo sites in O-MoS2, as confirmed by X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, high resolution transmission electron microscopy, and extended X-ray absorption fine structure characterization of various MoS2-based materials. O-MoS2 with abundant CUS Mo sites was found to efficiently catalyze the chemoselective reduction of nitroarenes to arylamines. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
KeywordMos2 Coordinative Unsaturated Mo Nitroarene Transfer Hydrogenation Formate Heterogeneous Catalysis
DOI10.1016/S1872-2067(16)62504-4
Indexed BySCI
Language英语
WOS IDWOS:000384156400018
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/26446
Collection中科院上海应用物理研究所2011-2018年
Corresponding AuthorWang, F (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China.
Recommended Citation
GB/T 7714
Zhang, CF,Wang, X,Li, MR,et al. Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2[J]. CHINESE JOURNAL OF CATALYSIS,2016,37(9):1569-1578.
APA Zhang, CF.,Wang, X.,Li, MR.,Zhang, ZX.,Wang, YH.,...&Wang, F .(2016).Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2.CHINESE JOURNAL OF CATALYSIS,37(9),1569-1578.
MLA Zhang, CF,et al."Chemoselective transfer hydrogenation to nitroarenes mediated by oxygen-implanted MoS2".CHINESE JOURNAL OF CATALYSIS 37.9(2016):1569-1578.
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