Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Fabrication and Characterization of High Stability (EDA)(FA)(2)[Pb3I10] Layered Perovskite Film | |
| Gao, YM; Jiang, WL; Yang, TY; Zuo, YZ; Gao, YM (reprint author), Jiangsu Univ Sci & Technol, Coll Mat Sci & Engn, Zhenjiang 212003, Peoples R China. | |
| 2016 | |
| Source Publication | JOURNAL OF INORGANIC MATERIALS
 |
| ISSN | 1000-324X |
| Volume | 31Issue:10Pages:1129-1134 |
| Subtype | 期刊论文 |
| Abstract | A new two-dimensional layered hybrid perovskite solar-cell absorber was synthesized by one-step method, using (EDA)I-2, (FA)I, and PbI2 with a 1 : 2 : 3 stoichiometric ratio in a solvent mixture of N, N-dimethylformamide(DMF). Ethylenediamine(EDA) cation was introduced into the perovskite lattice to synthesize a layered structure with improved resistance to the degradation by humidity in air. The effects of humidity and time on crystal structure, composition, morphology, and absorption spectra of (EDA)(FA)(2)[Pb3I10] and CH3NH3PbI3 were analyzed by in situ grazing incidence X-ray diffraction(GIXRD), X-ray diffraction (XRD), scanning electron microscope (SEM), atomic force microscope(AFM), and UV-Vis spectroscope. The results reveal that the prepared (EDA)(FA)(2)[Pb3I10] film is more moisture resistant than the CH3NH3PbI3 film which is widely used in the perovskite solar cell. SEM analysis reveals that the (EDA)(FA)(2)[Pb3I10] film has a layered structure, which can reduce the degradation caused by moisture. What's more, UV-Vis light absorption spectroscopy and atomic force microscopy(AFM) results show that the layered structure film is also a suitable absorber for perovskite solar cells. Photoluminescence spectrum(PL) reveals that bandgap of the (EDA)(FA)(2)[Pb3I10] film is 1.67 eV, which is close to the optimum value for solar photoelectric conversion. As compared to CH3NH3PbI3 film, the low-cost perovskite structure offers greater tunability on a molecular level for further material optimization and possibility for widely used in the future. |
| Keyword | One-step Method Perovskite Gixrd (Eda)(Fa)(2)[Pb3i10] |
| DOI | 10.15541/jim20160156 |
| Indexed By | SCI |
| Language | 中文 |
| WOS ID | WOS:000387529300020 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/26504 |
| Collection | 中科院上海应用物理研究所2011-2018年 |
| Corresponding Author | Gao, YM (reprint author), Jiangsu Univ Sci & Technol, Coll Mat Sci & Engn, Zhenjiang 212003, Peoples R China. |
| Recommended Citation GB/T 7714 | Gao, YM,Jiang, WL,Yang, TY,et al. Fabrication and Characterization of High Stability (EDA)(FA)(2)[Pb3I10] Layered Perovskite Film[J]. JOURNAL OF INORGANIC MATERIALS,2016,31(10):1129-1134. |
| APA | Gao, YM,Jiang, WL,Yang, TY,Zuo, YZ,&Gao, YM .(2016).Fabrication and Characterization of High Stability (EDA)(FA)(2)[Pb3I10] Layered Perovskite Film.JOURNAL OF INORGANIC MATERIALS,31(10),1129-1134. |
| MLA | Gao, YM,et al."Fabrication and Characterization of High Stability (EDA)(FA)(2)[Pb3I10] Layered Perovskite Film".JOURNAL OF INORGANIC MATERIALS 31.10(2016):1129-1134. |
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| Fabrication and Char（483KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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